Actinide Organometallic Complexes with π‐Ligands

Abstract: Recent developments and results from the organometallic chemistry of the actinides are reviewed. In the last one and a half years the structural data of about 15 organometallic complexes of transuranium actinides (Np or Pu) have been published, all involving π‐ligands in the coordination sphere of the metal ion. On the basis of these data, a comparison of these molecules is presented. Depending on the steric demands of the ligands, effects like the actinide contraction seem to be stronger or weaker in the structural features. This indicates that the interplay between the actinide ion and the π‐ligand is rather flexible, enabling the formation of stable bonds over a broad range of actinide ion oxidation states.

Object Details

• Location: Deutsche Nationalbibliothek Frankfurt am Main
• Extent: Online-Ressource
• Language: Englisch

References and Relationships

• Bibliographic citation: Actinide Organometallic Complexes with π‐Ligands ; volume:25 ; number:12 ; year:2019 ; pages:2927-2934 ; extent:8 ; Chemistry - a European journal ; 25, Heft 12 (2019), 2927-2934 (gesamt 8)

Contributors, Places and Time

• Creator: Walter, Olaf

Further information

• DOI: 10.1002/chem.201803413
• URN: urn:nbn:de:101:1-2022071508155884289012
• Rights: Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
• Last update: 15.08.2025, 7:29 AM CEST