Catalytic Photochemical Deracemization via Short‐Lived Intermediates
Abstract: Upon irradiation in the presence of a suitable chiral catalyst, racemic compound mixtures can be converted into enantiomerically pure compounds with the same constitution. The process is called photochemical deracemization and involves the formation of short‐lived intermediates. By opening different reaction channels for the forward reaction to the intermediate and for the re‐constitution of the chiral molecule, the entropically disfavored process becomes feasible. Since the discovery of the first photochemical deracemization in 2018, the field has been growing rapidly. This review comprehensively covers the research performed in the area and discusses current developments. It is subdivided according to the mode of action and the respective substrate classes. The focus of this review is on the scope of the individual reactions and on a discussion of the mechanistic details underlying the presented reaction.
- Standort
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Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
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Online-Ressource
- Sprache
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Englisch
- Erschienen in
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Catalytic Photochemical Deracemization via Short‐Lived Intermediates ; day:19 ; month:09 ; year:2023 ; extent:19
Angewandte Chemie / International edition. International edition ; (19.09.2023) (gesamt 19)
- Urheber
- DOI
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10.1002/anie.202308241
- URN
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urn:nbn:de:101:1-2023092015161836852756
- Rechteinformation
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
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14.08.2025, 11:02 MESZ
Datenpartner
Deutsche Nationalbibliothek. Bei Fragen zum Objekt wenden Sie sich bitte an den Datenpartner.
Beteiligte
- Großkopf, Johannes
- Bach, Thorsten
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