Comparison of temperature-dependent calibration methods of an instrument to measure OH and HO<sub>2</sub> radicals using laser-induced fluorescence spectroscopy
Abstract 2, following conversion to OH, over a wide variety of conditions, on different platforms and in simulation chambers. Conventional calibration of HOx (OH + 2) instruments has mainly relied on a single method, generating known concentrations of HOx from H2 O vapour photolysis in a flow of zero air impinging just outside the sample inlet (S HO x = C HO x x ], where S HO x C HO x x measurements in the Highly Instrumented Reactor for Atmospheric Chemistry (HIRAC) at the University of Leeds has been used to examine the sensitivity of FAGE to external gas temperatures (266–348 K). C OH (relative to the value at 293 K) of (0.0059 ± 0.0015) K- 1 C HO 2 0.014 ± 0.013) K- 1 σ C OH was also determined by observing the decay of hydrocarbons (typically cyclohexane) caused by OH reactions giving C OH 0.0038 ± 0.0007) K- 1 C HO 2 2 recombination with the temperature dependence of C HO 2 0.0064 ± 0.0034) K- 1 C HO x x number density, quenching, the relative population of the probed OH rotational level and HOx transmission from the inlet to the detection axis. The first three terms can be calculated and, in combination with the measured values of C HO x x transmission increases with temperature. Comparisons with other instruments and the implications of this work are discussed.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Comparison of temperature-dependent calibration methods of an instrument to measure OH and HO2 radicals using laser-induced fluorescence spectroscopy ; volume:16 ; number:19 ; year:2023 ; pages:4375-4390 ; extent:16
Atmospheric measurement techniques ; 16, Heft 19 (2023), 4375-4390 (gesamt 16)
- Creator
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Winiberg, Frank A. F.
Warman, William J.
Brumby, Charlotte A.
Boustead, Graham
Bejan, Iustinian G.
Speak, Thomas H.
Heard, Dwayne E.
Stone, Daniel
Seakins, Paul W.
- DOI
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10.5194/amt-16-4375-2023
- URN
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urn:nbn:de:101:1-2023101204362769414956
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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14.08.2025, 10:57 AM CEST
Data provider
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Associated
- Winiberg, Frank A. F.
- Warman, William J.
- Brumby, Charlotte A.
- Boustead, Graham
- Bejan, Iustinian G.
- Speak, Thomas H.
- Heard, Dwayne E.
- Stone, Daniel
- Seakins, Paul W.
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Comparison of temperature dependent calibration methods of an instrument to measure OH and HO<sub>2</sub> radicals using laser-induced fluorescence spectroscopy
Detection of HO 2 by laser-induced fluorescence: calibration and interferences from RO 2 radicals
Validation of the calibration of a laser-induced fluorescence instrument for the measurement of OH radicals in the atmosphere
Atmospheric calibration for sub-millimeter radio astronomy
Sub-camera calibration of a Penta-camera
SUB-CAMERA CALIBRATION OF A PENTA-CAMERA
Laser-induced magnetization precession in the magnetite Fe<sub>3</sub>O<sub>4</sub> in the vicinity of a spin-reorientation transition
Towards a hygroscopic growth calibration for low-cost PM<sub>2.5</sub> sensors
Observational operator for fair model calibration with ground NO<sub>2</sub> measurements
Performance evaluation of MOMA – a remote network calibration technique for PM<sub>2.5</sub> and PM<sub>10</sub> sensors
Experimental chemical budgets of OH, HO<sub>2</sub>, and RO<sub>2</sub> radicals in rural air in western Germany during the JULIAC campaign 2019
Experimental chemical budgets of OH, HO<sub>2</sub> and RO<sub>2</sub> radicals in rural air in West-Germany during the JULIAC campaign 2019
Comparison of temperature dependent calibration methods of an instrument to measure OH and HO<sub>2</sub> radicals using laser-induced fluorescence spectroscopy
Detection of HO 2 by laser-induced fluorescence: calibration and interferences from RO 2 radicals
Validation of the calibration of a laser-induced fluorescence instrument for the measurement of OH radicals in the atmosphere
Atmospheric calibration for sub-millimeter radio astronomy
Sub-camera calibration of a Penta-camera
SUB-CAMERA CALIBRATION OF A PENTA-CAMERA
Laser-induced magnetization precession in the magnetite Fe<sub>3</sub>O<sub>4</sub> in the vicinity of a spin-reorientation transition
Towards a hygroscopic growth calibration for low-cost PM<sub>2.5</sub> sensors
Observational operator for fair model calibration with ground NO<sub>2</sub> measurements
Performance evaluation of MOMA – a remote network calibration technique for PM<sub>2.5</sub> and PM<sub>10</sub> sensors
Experimental chemical budgets of OH, HO<sub>2</sub>, and RO<sub>2</sub> radicals in rural air in western Germany during the JULIAC campaign 2019