Enantiospecific Synthesis of 1,3‐Disubstituted Allenes from Propargylic Carbonates through a Borylation‐1,2‐Elimination Process
Abstract: An array of enantioenriched vinyl boronates bearing an allylic carbonate moiety have been prepared through selective hydroboration of propargyl carbonates. Treatment of these vinyl boronates with TBAF in THF affords enantioenriched 1,3‐disubstituted allenes through a novel 1,2‐anti elimination in good yields and high enantiospecificities.
- Standort
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Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
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Online-Ressource
- Sprache
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Englisch
- Erschienen in
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Enantiospecific Synthesis of 1,3‐Disubstituted Allenes from Propargylic Carbonates through a Borylation‐1,2‐Elimination Process ; day:23 ; month:11 ; year:2023 ; extent:7
Advanced synthesis & catalysis ; (23.11.2023) (gesamt 7)
- Urheber
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Jarava‐Barrera, Carlos
Parra, Alejandro
Quesada, Sergio
Orgaz‐Gordillo, Sergio
Fernández de la Pradilla, Roberto
Viso, Alma
Teresa, Javier
Alonso, Inés
Tortosa, Mariola
- DOI
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10.1002/adsc.202300813
- URN
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urn:nbn:de:101:1-2023112414272761808315
- Rechteinformation
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
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15.08.2025, 07:34 MESZ
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Beteiligte
- Jarava‐Barrera, Carlos
- Parra, Alejandro
- Quesada, Sergio
- Orgaz‐Gordillo, Sergio
- Fernández de la Pradilla, Roberto
- Viso, Alma
- Teresa, Javier
- Alonso, Inés
- Tortosa, Mariola
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