Superior Metal‐Organic Framework Activation with Dimethyl Ether
Abstract: Metal–organic frameworks (MOFs) are demonstrated to be readily activated by treatment with the low surface tension, low boiling point solvent dimethyl ether (DME). The mildness of the method enables access to high surface areas by avoiding structural changes in the framework that often plague thermal activation methods. A distinction from previous methods is that DME activation succeeds for materials with coordinatively unsaturated sites (CUS) and non‐CUS MOFs as well. DME displaces solvent molecules occupying the pores of the MOF as well as those coordinated to metal centers; reducing evacuation temperature by using a coordinating, yet highly volatile guest enables low temperature activation with structural retention as demonstrated surface area measurements that match or exceed existing activation protocols.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Superior Metal‐Organic Framework Activation with Dimethyl Ether ; day:23 ; month:11 ; year:2022 ; extent:1
Angewandte Chemie ; (23.11.2022) (gesamt 1)
- Creator
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Wright, Keenan R.
Nath, Karabi
Matzger, Adam J.
- DOI
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10.1002/ange.202213190
- URN
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urn:nbn:de:101:1-2022112414235326968955
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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15.08.2025, 7:23 AM CEST
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Associated
- Wright, Keenan R.
- Nath, Karabi
- Matzger, Adam J.
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Continuous anhydrous synthesis of oxymethylene dimethyl ethers by reaction of dimethyl ether with molecular formaldehyde
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CO2 hydrogenation to methanol and dimethyl ether
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Diethylene glycol dimethyl ether : (Bis(2-methoxyethyl)-ether)
Terahertz spectroscopy of dimethyl ether
Continuous anhydrous synthesis of oxymethylene dimethyl ethers by reaction of dimethyl ether with molecular formaldehyde
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