Product Peroxidation Inhibition in Methane Photooxidation into Methanol

Abstract: Methane photooxidation into methanol offers a practical approach for the generation of high‐value chemicals and the efficient storage of solar energy. However, the propensity for C─H bonds in the desired products to cleave more easily than those in methane molecules results in a continuous dehydrogenation process, inevitably leading to methanol peroxidation. Consequently, inhibiting methanol peroxidation is perceived as one of the most formidable challenges in the field of direct conversion of methane to methanol. This review offers a thorough overview of the typical mechanisms involved radical mechanism and active site mechanism and the regulatory methods employed to inhibit product peroxidation in methane photooxidation. Additionally, several perspectives on the future research direction of this crucial field are proposed.

Location
Deutsche Nationalbibliothek Frankfurt am Main
Extent
Online-Ressource
Language
Englisch

Bibliographic citation
Product Peroxidation Inhibition in Methane Photooxidation into Methanol ; day:17 ; month:01 ; year:2024 ; extent:15
Advanced science ; (17.01.2024) (gesamt 15)

Creator
Cao, Yuehan
Huang, Zeai
Han, Chunqiu
Zhou, Ying

DOI
10.1002/advs.202306891
URN
urn:nbn:de:101:1-2024011814165813541771
Rights
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Last update
15.08.2025, 7:23 AM CEST

Data provider

This object is provided by:
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.

Associated

  • Cao, Yuehan
  • Huang, Zeai
  • Han, Chunqiu
  • Zhou, Ying

Other Objects (12)