Synthesis of Waterborne Anticorrosive Coatings Based on The Incorporation of Phosphate Groups to Polyurethane‐Acrylate Hybrids

Abstract: In this work, solvent‐free waterborne polyurethane‐poly (meth) acrylate hybrid dispersions that can be used to formulate anticorrosive paints are synthesized. To achieve the anticorrosive protection, a phosphate containing polymerizable surfactant, Sipomer PAM 200 is incorporated to the hybrids. The presence of phosphate groups can produce an iron phosphate passivation layer to provide coatings with anticorrosive properties. These properties are tested in both mild and harsh corrosive environments. It is observed that when the films are dried at 60% relative humidity conditions, very poor anticorrosive protection is achieved because no phosphatization is obtained, but increasing the humidity to 85% during the drying step allows the formation of the passivation layer providing good anticorrosive properties.

Location
Deutsche Nationalbibliothek Frankfurt am Main
Extent
Online-Ressource
Language
Englisch

Bibliographic citation
Synthesis of Waterborne Anticorrosive Coatings Based on The Incorporation of Phosphate Groups to Polyurethane‐Acrylate Hybrids ; day:03 ; month:04 ; year:2023 ; extent:13
Macromolecular reaction engineering ; (03.04.2023) (gesamt 13)

Creator
Barquero, Aitor
Llorente, Oihane
Minudri, Daniela
Paulis, María
Leiza, Jose Ramon

DOI
10.1002/mren.202300015
URN
urn:nbn:de:101:1-2023040315355820491790
Rights
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Last update
14.08.2025, 10:57 AM CEST

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Associated

  • Barquero, Aitor
  • Llorente, Oihane
  • Minudri, Daniela
  • Paulis, María
  • Leiza, Jose Ramon

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