Designed from Biobased Materials for Recycling: Imine‐Based Covalent Adaptable Networks

Abstract: Turning thermosets into fully sustainable materials requires utilization of biobased raw materials and design for easy recyclability. Here, dynamic covalent chemistry for fabrication of covalent adaptable networks (CANs) could be an enabling tool. CAN thermosets ideally combine the positive material properties of thermosets with thermal recyclability of linear thermoplastics. Among the dynamic covalent bonds, imine bond, also called Schiff base, can participate in both dissociative and associative pathways. This induces potential for chemical recyclability, thermal reprocessability and self‐healing. This review presents an overview of the current research front of biobased thermosets fabricated by Schiff base chemistry. The discussed materials are categorized on the basis of the employed biobased components. The chemical approaches for the synthesis and curing of the resins, as well as the resulting properties and recyclability of the obtained thermosets are described and discussed. Finally, challenges and future perspectives are briefly summarized.

Standort
Deutsche Nationalbibliothek Frankfurt am Main
Umfang
Online-Ressource
Sprache
Englisch

Erschienen in
Designed from Biobased Materials for Recycling: Imine‐Based Covalent Adaptable Networks ; day:04 ; month:02 ; year:2022 ; extent:17
Macromolecular rapid communications ; (04.02.2022) (gesamt 17)

Urheber
Liguori, Anna
Hakkarainen, Minna

DOI
10.1002/marc.202100816
URN
urn:nbn:de:101:1-2022020414503783277250
Rechteinformation
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Letzte Aktualisierung
15.08.2025, 07:25 MESZ

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Beteiligte

  • Liguori, Anna
  • Hakkarainen, Minna

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