Enhanced Colorimetric Detection of Volatile Organic Compounds Using a Dye‐Incorporated Photonic Crystal‐Based Sensor Array
Abstract: Chemoresponsive dyes offer the potential to selectively detect volatile organic compounds (VOCs) unique to certain disease states. Among different VOC sensing techniques, colorimetric sensing offers the advantage of facile recognition. However, it is often challenging to discern the color changes by the naked eye. Here, highly sensitive colorimetric VOC sensor arrays from dye‐incorporated colloidal photonic crystals (dye‐cPhCs) are reported. cPhCs are scalably fabricated on a 4‐inch wafer by spin‐coating of silica nanoparticles (NPs) dispersed in a photo‐cross‐linkable monomer, where the gradient shear flow along the film thickness creates densely‐packed square arrays of NPs in the top layers, whereas the bulk is quasi‐amorphous with larger periodicities. The broadened reflection peak allows for augmented dye absorption originating from the overlap between the photonic bandgap edge of the cPhC and the dye absorption peak, leading to a more noticeable color change upon exposure to VOCs. The sensor array generates distinct color difference maps for acetaldehyde, acetone, and acetic acid, respectively, without any data amplification. The limit of detection for acetaldehyde, acetone, and acetic acid is 1, 0.1, and 0.02 ppm, respectively. Moreover, VOC can be diagonalized by visually intuitive pattern recognition, and principal component analysis at reduced dimensionality is demonstrated.
- Location
-
Deutsche Nationalbibliothek Frankfurt am Main
- Extent
-
Online-Ressource
- Language
-
Englisch
- Bibliographic citation
-
Enhanced Colorimetric Detection of Volatile Organic Compounds Using a Dye‐Incorporated Photonic Crystal‐Based Sensor Array ; day:10 ; month:09 ; year:2024 ; extent:13
Advanced materials ; (10.09.2024) (gesamt 13)
- Creator
-
Nah, So Hee
Kim, Jong Bin
Chui, Hiu Ning Tiffany
Suh, Yeonjoon
Yang, Shu
- DOI
-
10.1002/adma.202409297
- URN
-
urn:nbn:de:101:1-2409101427005.544687734097
- Rights
-
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
-
15.08.2025, 7:24 AM CEST
Data provider
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Associated
- Nah, So Hee
- Kim, Jong Bin
- Chui, Hiu Ning Tiffany
- Suh, Yeonjoon
- Yang, Shu
Other Objects (12)
Soft Photonic Fibers for Colorimetric Solvent Vapor Sensing
Organohalogenochromism: Toward Colorimetric Detection of Volatile Organic Halogen Compounds
Reading dye-based colorimetric inks: achieving color consistency using color QR codes
Dye-Binding Method for Rapid Colorimetric Determination of the Cholestasis Charaterizing Lipoprotein-X
Azobenzene dye-coupled quadruply hydrogen-bonding modules as colorimetric indicators for supramolecular interactions
Nonequilibrium Bose condensation in a pumped dye-filled photonic cavity
Influence of the matrix environment on the optical properties of incorporated dye molecules
Near infrared fluorescent imaging of brain tumor with IR780 dye incorporated phospholipid nanoparticles
Reconfigurable nonlinear photonic activation function for photonic neural network based on non-volatile opto-resistive RAM switch
Dye-incorporated coordination polymers for direct photocatalytic trifluoromethylation of aromatics at metabolically susceptible positions
Joker Incorporated
Non-volatile photonic-electronic memory via 3D monolithic ferroelectric-silicon ring resonator
Soft Photonic Fibers for Colorimetric Solvent Vapor Sensing
Organohalogenochromism: Toward Colorimetric Detection of Volatile Organic Halogen Compounds
Reading dye-based colorimetric inks: achieving color consistency using color QR codes
Dye-Binding Method for Rapid Colorimetric Determination of the Cholestasis Charaterizing Lipoprotein-X
Azobenzene dye-coupled quadruply hydrogen-bonding modules as colorimetric indicators for supramolecular interactions
Nonequilibrium Bose condensation in a pumped dye-filled photonic cavity
Influence of the matrix environment on the optical properties of incorporated dye molecules
Near infrared fluorescent imaging of brain tumor with IR780 dye incorporated phospholipid nanoparticles
Reconfigurable nonlinear photonic activation function for photonic neural network based on non-volatile opto-resistive RAM switch
Dye-incorporated coordination polymers for direct photocatalytic trifluoromethylation of aromatics at metabolically susceptible positions
Joker Incorporated
Non-volatile photonic-electronic memory via 3D monolithic ferroelectric-silicon ring resonator
Soft Photonic Fibers for Colorimetric Solvent Vapor Sensing
Organohalogenochromism: Toward Colorimetric Detection of Volatile Organic Halogen Compounds
Reading dye-based colorimetric inks: achieving color consistency using color QR codes
Dye-Binding Method for Rapid Colorimetric Determination of the Cholestasis Charaterizing Lipoprotein-X
Azobenzene dye-coupled quadruply hydrogen-bonding modules as colorimetric indicators for supramolecular interactions
Nonequilibrium Bose condensation in a pumped dye-filled photonic cavity
Influence of the matrix environment on the optical properties of incorporated dye molecules
Near infrared fluorescent imaging of brain tumor with IR780 dye incorporated phospholipid nanoparticles
Reconfigurable nonlinear photonic activation function for photonic neural network based on non-volatile opto-resistive RAM switch
Dye-incorporated coordination polymers for direct photocatalytic trifluoromethylation of aromatics at metabolically susceptible positions
Joker Incorporated