Biomimetic Supramolecular Fibers Exhibit Water‐Induced Supercontraction

Abstract: Spider silk is a fascinating material, combining high strength and elasticity that outperforms most synthetic fibers. Another intriguing feature of spider silk is its ability to “supercontract,” shrinking up to 50% when exposed to water. This is likely on account of the entropy‐driven recoiling of secondary structured proteins when water penetrates the spider silk. In contrast, humidity‐driven contraction in synthetic fibers is difficult to achieve. Here, inspired by the spider silk model, a supercontractile fiber (SCF), which contracts up to 50% of its original length at high humidity, comparable to spider silk, is reported. The fiber exhibits up to 300% uptake of water by volume, confirmed via environmental scanning electron microscopy. Interestingly, the SCF exhibits tunable mechanical properties by varying humidity, which is reflected by the prolonged failure strain and the reversible damping capacity. This smart supramolecular fiber material provides a new opportunity of fabricating biomimetic muscle for diverse applications.

Standort
Deutsche Nationalbibliothek Frankfurt am Main
Umfang
Online-Ressource
Sprache
Englisch

Erschienen in
Biomimetic Supramolecular Fibers Exhibit Water‐Induced Supercontraction ; volume:30 ; number:27 ; year:2018 ; extent:5
Advanced materials ; 30, Heft 27 (2018) (gesamt 5)

Urheber
Wu, Yuchao
Shah, Darshil U.
Wang, Baoyuan
Liu, Ji
Ren, Xiaohe
Ramage, Michael H.
Scherman, Oren A.

DOI
10.1002/adma.201707169
URN
urn:nbn:de:101:1-2022090108431099768374
Rechteinformation
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Letzte Aktualisierung
15.08.2025, 07:33 MESZ

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Beteiligte

  • Wu, Yuchao
  • Shah, Darshil U.
  • Wang, Baoyuan
  • Liu, Ji
  • Ren, Xiaohe
  • Ramage, Michael H.
  • Scherman, Oren A.

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