In Situ Formation of Platinum‐Carbon Catalysts in Propane Dehydrogenation
Abstract: The catalytic production of propylene via propane dehydrogenation (PDH) is a key reaction in the chemical industry. By combining operando transmission electron microscopy with density functional theory analysis, we show that the intercalation and ordering of carbon on Pt interstitials to form Pt−C solid solutions is relevant for increasing propylene production. More specifically, we found that at the point of enhanced propylene formation, the structure of platinum nanoparticles is transformed into a transient caesium chloride‐type Pt−C polymorph. At more elevated temperatures, the zincblende and rock salt polymorphs seemingly coexist. When propylene production was highest, multiple crystal structures consisting of Pt and carbon were occasionally found to coexist in one individual nanoparticle, distorting the Pt lattice. Catalyst coking was detected at all stages of the reaction, but did initially not affect all particles. These findings could lead to the development of novel synthesis strategies towards tailoring highly efficient PDH catalysts.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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In Situ Formation of Platinum‐Carbon Catalysts in Propane Dehydrogenation ; day:10 ; month:05 ; year:2024 ; extent:10
Angewandte Chemie ; (10.05.2024) (gesamt 10)
- Creator
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Nerl, Hannah C.
Plodinec, Milivoj
Götsch, Thomas
Skorupska, Katarzyna
Schlögl, Robert
Jones, Travis E.
Lunkenbein, Thomas
- DOI
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10.1002/ange.202319887
- URN
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urn:nbn:de:101:1-2405101427531.685751018735
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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14.08.2025, 10:53 AM CEST
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Associated
- Nerl, Hannah C.
- Plodinec, Milivoj
- Götsch, Thomas
- Skorupska, Katarzyna
- Schlögl, Robert
- Jones, Travis E.
- Lunkenbein, Thomas
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In Situ Formation of Platinum‐Carbon Catalysts in Propane Dehydrogenation
Structure‐Activity Relationships in Highly Active Platinum‐Tin MFI‐type Zeolite Catalysts for Propane Dehydrogenation
Combining CO2 reduction with propane oxidative dehydrogenation over bimetallic catalysts
Confining platinum clusters in indium-modified ZSM-5 zeolite to promote propane dehydrogenation
Investigation of Aging Mechanism of Pt‐ZSM‐5 Catalysts for Non‐Oxidative Propane Dehydrogenation
Thermally Stable and Regenerable Platinum–Tin Clusters for Propane Dehydrogenation Prepared by Atom Trapping on Ceria
Thermally Stable and Regenerable Platinum–Tin Clusters for Propane Dehydrogenation Prepared by Atom Trapping on Ceria
New insights into the oxidative dehydrogenation of propane and ethane on supported vanadium oxide catalysts
Supported mono- and bimetallic catalysts for the $CO_2}$ - oxidative dehydrogenation of propane to propylene
High performance (VOx)(n)-( TiOx)(m)/SBA-15 catalysts for the oxidative dehydrogenation of propane
Design of PtZn nanoalloy catalysts for propane dehydrogenation through interface tailoring via atomic layer deposition
High-entropy intermetallics on ceria as efficient catalysts for the oxidative dehydrogenation of propane using CO2
In Situ Formation of Platinum‐Carbon Catalysts in Propane Dehydrogenation
Structure‐Activity Relationships in Highly Active Platinum‐Tin MFI‐type Zeolite Catalysts for Propane Dehydrogenation
Combining CO2 reduction with propane oxidative dehydrogenation over bimetallic catalysts
Confining platinum clusters in indium-modified ZSM-5 zeolite to promote propane dehydrogenation
Investigation of Aging Mechanism of Pt‐ZSM‐5 Catalysts for Non‐Oxidative Propane Dehydrogenation
Thermally Stable and Regenerable Platinum–Tin Clusters for Propane Dehydrogenation Prepared by Atom Trapping on Ceria
Thermally Stable and Regenerable Platinum–Tin Clusters for Propane Dehydrogenation Prepared by Atom Trapping on Ceria
New insights into the oxidative dehydrogenation of propane and ethane on supported vanadium oxide catalysts
Supported mono- and bimetallic catalysts for the $CO_2}$ - oxidative dehydrogenation of propane to propylene
High performance (VOx)(n)-( TiOx)(m)/SBA-15 catalysts for the oxidative dehydrogenation of propane
Design of PtZn nanoalloy catalysts for propane dehydrogenation through interface tailoring via atomic layer deposition