Deoxygenative Intramolecular Minisci‐Type Reaction to Access Fused Heterocyclic Scaffolds

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Abstract: Herein, we present a straightforward strategy for the synthesis of fused heterocycles through a deoxygenative, intramolecular Minisci‐type reaction. This approach grants access to complex polycyclic scaffolds in three steps from readily available starting materials, such as chlorinated heteroarenes and 1,3‐diols. The use of saccharide derivatives as the starting 1,3‐diol motif allows for the synthesis of novel heterocyclic scaffolds with excellent diastereoselectivity and formal retention of configuration at the newly formed C−C bond.

Location: Deutsche Nationalbibliothek Frankfurt am Main

Extent: Online-Ressource

Language: Englisch

Bibliographic citation: Deoxygenative Intramolecular Minisci‐Type Reaction to Access Fused Heterocyclic Scaffolds ; day:22 ; month:11 ; year:2022 ; extent:1
European journal of organic chemistry ; (22.11.2022) (gesamt 1)

Creator: Aguilar Troyano, Francisco José
Anwar, Khadijah
Mohr, Fabian
Robert, Guillaume
Gómez-Suárez, Adrián

DOI: 10.1002/ejoc.202201176

URN: urn:nbn:de:101:1-2022112314162677544253

Rights: Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.

Last update: 15.08.2025, 7:30 AM CEST

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Deoxygenative Intramolecular Minisci‐Type Reaction to Access Fused Heterocyclic Scaffolds

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