Photochemical O−H Functionalization Reactions of Cyclic Diazoamides

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Abstract: Herein, we describe the photochemical O−H functionalization reaction of acidic alcohols with cyclic diazoamides. We studied the O−H functionalization reaction of different fluorinated and non‐fluorinated alcohols to give the corresponding ether products in high yields (43 examples, up to 97% yield). Furthermore, we performed studies to evaluate a photoexcited proton transfer reaction pathway in comparison to classic carbene transfer reactions.

Location: Deutsche Nationalbibliothek Frankfurt am Main

Extent: Online-Ressource

Language: Englisch

Bibliographic citation: Photochemical O−H Functionalization Reactions of Cyclic Diazoamides ; volume:362 ; number:21 ; year:2020 ; pages:4716-4722 ; extent:7
Advanced synthesis & catalysis ; 362, Heft 21 (2020), 4716-4722 (gesamt 7)

Creator: Empel, Claire
Verspeek, Dennis
Jana, Sripati
Koenigs, Rene M.

DOI: 10.1002/adsc.202000818

URN: urn:nbn:de:101:1-2022060616035956276269

Rights: Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.

Last update: 15.08.2025, 7:31 AM CEST

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Associated

Empel, Claire
Verspeek, Dennis
Jana, Sripati
Koenigs, Rene M.

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