Electrochemical Formation and Removal of Homogeneous Cu Catalysts
Abstract: Transition metal ions and their complexes play a crucial role in homogeneous catalysis. These catalysts are pivotal for the production of, for example, fine chemicals and pharmaceuticals. Nevertheless, because of the homogeneous nature of these catalysts, their extraction and removal from the crude reaction mixture is cumbersome. Here, we propose an alternative approach where metal‐based homogeneous catalysts are generated electrochemically from a metallic anode (Cu), followed by their use without current, and finally again electrochemically deposited on the cathode. The generated Cu ions were used as catalysts in three different reactions of lauroyl peroxide: one ligand‐free (coupling with dienes), one without ligand but with a heteroatom containing substrate (coupling with toluidine and styrene) and one in the presence of 1,10‐phen as ligand (coupling with indazole). In the first two cases, performance of the electrochemically generated catalysts was similar to those reported in literature for classically prepared homogeneous catalysts, whereas in the last case a new reaction was observed. After reaction, the homogeneous copper catalyst could be efficiently removed electrochemically: 99% of the copper could be removed for the ligand‐free reaction, 97% for the amine coupling, whereas 89% of copper could be removed for the reaction containing N‐heterocycle and 1,10‐phenanthroline.
- Standort
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Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
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Online-Ressource
- Sprache
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Englisch
- Erschienen in
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Electrochemical Formation and Removal of Homogeneous Cu Catalysts ; day:18 ; month:10 ; year:2024 ; extent:5
ChemCatChem ; (18.10.2024) (gesamt 5)
- Urheber
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Pirgach, Dmitry A.
Miloserdov, Fedor M.
van Es, Daan S.
Bruijnincx, Pieter C. A.
Bitter, Johannes H.
- DOI
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10.1002/cctc.202401473
- URN
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urn:nbn:de:101:1-2410191422308.435805969978
- Rechteinformation
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
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15.08.2025, 07:25 MESZ
Datenpartner
Deutsche Nationalbibliothek. Bei Fragen zum Objekt wenden Sie sich bitte an den Datenpartner.
Beteiligte
- Pirgach, Dmitry A.
- Miloserdov, Fedor M.
- van Es, Daan S.
- Bruijnincx, Pieter C. A.
- Bitter, Johannes H.
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