Molecular Design Strategies for Electrochemical Behavior of Aromatic Carbonyl Compounds in Organic and Aqueous Electrolytes

Abstract: To sustainably satisfy the growing demand for energy, organic carbonyl compounds (OCCs) are being widely studied as electrode active materials for batteries owing to their high capacity, flexible structure, low cost, environmental friendliness, renewability, and universal applicability. However, their high solubility in electrolytes, limited active sites, and low conductivity are obstacles in increasing their usage. Here, the nucleophilic addition reaction of aromatic carbonyl compounds (ACCs) is first used to explain the electrochemical behavior of carbonyl compounds during charge–discharge, and the relationship of the molecular structure and electrochemical properties of ACCs are discussed. Strategies for molecular structure modifications to improve the performance of ACCs, i.e., the capacity density, cycle life, rate performance, and voltage of the discharge platform, are also elaborated. ACCs, as electrode active materials in aqueous solutions, will become a future research hotspot. ACCs will inevitably become sustainable green materials for batteries with high capacity density and high power density.

Location
Deutsche Nationalbibliothek Frankfurt am Main
Extent
Online-Ressource
Language
Englisch

Bibliographic citation
Molecular Design Strategies for Electrochemical Behavior of Aromatic Carbonyl Compounds in Organic and Aqueous Electrolytes ; volume:6 ; number:17 ; year:2019 ; extent:37
Advanced science ; 6, Heft 17 (2019) (gesamt 37)

Creator
Peng, Huiling
Yu, Qianchuan
Wang, Shengping
Kim, Jeonghun
Rowan, Alan E.
Nanjundan, Ashok Kumar
Yamauchi, Yusuke
Yu, Jingxian

DOI
10.1002/advs.201900431
URN
urn:nbn:de:101:1-2022072506411704530469
Rights
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Last update
15.08.2025, 7:27 AM CEST

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Associated

  • Peng, Huiling
  • Yu, Qianchuan
  • Wang, Shengping
  • Kim, Jeonghun
  • Rowan, Alan E.
  • Nanjundan, Ashok Kumar
  • Yamauchi, Yusuke
  • Yu, Jingxian

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