Zwitterion‐Catalyzed Ring‐Opening of Epoxides with Carboxylic Acids

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Abstract: 1,2‐Diol mono‐esters are useful building blocks in various areas. Herein, we report an efficient zwitterion‐catalyzed epoxide ring‐opening with carboxylic acids to give 1,2‐diol monoesters. The catalytic protocol was applicable to a wide range of substrates. In addition, aziridine instead of epoxide could be used. The zwitterionic catalyst could be recycled by a simple aqueous extraction. The synthetic utilities of the 1,2‐diol monoesters have been demonstrated.

Location: Deutsche Nationalbibliothek Frankfurt am Main

Extent: Online-Ressource

Language: Englisch

Bibliographic citation: Zwitterion‐Catalyzed Ring‐Opening of Epoxides with Carboxylic Acids ; day:27 ; month:01 ; year:2023 ; extent:6
Asian journal of organic chemistry ; (27.01.2023) (gesamt 6)

Creator: Qiang, Shengsheng
Hu, Rong‐Bin
Yeung, Ying‐Yeung

DOI: 10.1002/ajoc.202200673

URN: urn:nbn:de:101:1-2023012814080572840193

Rights: Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.

Last update: 15.08.2025, 7:20 AM CEST

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Qiang, Shengsheng
Hu, Rong‐Bin
Yeung, Ying‐Yeung

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Zwitterion‐Catalyzed Ring‐Opening of Epoxides with Carboxylic Acids

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Other Objects (12)

Ring-Opening Hydroboration of Epoxides Catalyzed by a Silica-Supported Organolanthanum Complex

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DBU‐Catalyzed Ring‐Opening and Retro‐Claisen Fragmentation of Dihydropyranones §

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DBU‐Catalyzed Ring‐Opening and Retro‐Claisen Fragmentation of Dihydropyranones §

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