Mixtures of Acid‐ and Base‐Functionalized Microparticles for One‐Pot Cascade Reaction
Abstract: This study reports on the synthesis of surface‐protected acid and base microparticles via surfactant‐free emulsion polymerization. The protective layer allows to form particle mixtures with both colloidal catalysts that show excellent performance in a well‐established model cascade reaction involving an acid‐catalyzed deacetalization and a subsequent base‐catalyzed Knoevenagel condensation. Compared to nanoreactors that contain both catalysts, the colloidal mixture shows comparable reaction kinetics despite the local separation of both catalysts onto separate particles. Since the synthesis of individual microparticles requires less steps, is scalable, and more versatile in terms of catalyst variation, colloidal mixtures are certainly an alternative to multifunctional nanoreactors, making them attractive for practical applications.
- Standort
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Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
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Online-Ressource
- Sprache
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Englisch
- Erschienen in
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Mixtures of Acid‐ and Base‐Functionalized Microparticles for One‐Pot Cascade Reaction ; day:05 ; month:05 ; year:2023 ; extent:4
Macromolecular rapid communications ; (05.05.2023) (gesamt 4)
- Urheber
- DOI
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10.1002/marc.202300063
- URN
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urn:nbn:de:101:1-2023050515353991622716
- Rechteinformation
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
- 14.08.2025, 10:49 MESZ
Datenpartner
Deutsche Nationalbibliothek. Bei Fragen zum Objekt wenden Sie sich bitte an den Datenpartner.
Beteiligte
- Chen, Chen
- Wong, Chin Ken
- Gröschel, André H.
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