Study on the unsaturated hydrogen bond behavior of bio-based polyamide 56

Abstract: In this paper, the unsaturated hydrogen bonds (H-bonds) of the bio-based polyamide 56 (PA56) with an odd-even unit structure were analyzed by infrared spectroscopy. It was proved that the bio-based PA56 had less saturated H-bonds, which became attenuated and blue-shifted at the temperature exceeding 260°C. Besides, as H-bond was decayed and broken, new unsaturated H-bonds readily formed. Moreover, the experimental results obtained strongly indicate that the unsaturated H-bonds of bio-based polyamide 56 could react with polar metal oxides. Besides, the intercalation of montmorillonite was found to have a significant influence on the hydrogen bond between polymer chains.

Standort
Deutsche Nationalbibliothek Frankfurt am Main
Umfang
Online-Ressource
Sprache
Englisch

Erschienen in
Study on the unsaturated hydrogen bond behavior of bio-based polyamide 56 ; volume:19 ; number:1 ; year:2019 ; pages:23-31 ; extent:9
e-Polymers ; 19, Heft 1 (2019), 23-31 (gesamt 9)

Urheber
Zhang, Shouyun
Ma, Jinghong

DOI
10.1515/epoly-2019-0004
URN
urn:nbn:de:101:1-2412151601295.559419333537
Rechteinformation
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Letzte Aktualisierung
15.08.2025, 07:30 MESZ

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Beteiligte

  • Zhang, Shouyun
  • Ma, Jinghong

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