Konferenzbeitrag

Effect of graphene oxide on the thermal properties of bovine hide powders

Content: Graphene oxide (GO) is one of the most interesting nanomaterials in recent years. In order to explore its potential application in leather making process, a study on evaluating the effects of GO on the thermal stability and decomposition kinetics of bovine hide powders (HP) was performed by thermogravimetry. It was shown that the GO-doped hide powders (GO-HP) exhibit better thermal stability than those of raw hide powders. The kinetic and mechanism analysis of the decomposition stage used an integrated procedure involving model-free methods and universal master-plots method. Various methods were employed to calculate the activation energy of the fibers, including the Flynn-Wall-Ozawa (FWO), Modified Kissinger-Akahira-Sunose (MKAS) and Friedman methods. The activation energy values of GO-HP and raw hide powder were found to be 240.5 and 184.7 kJ/mol, respectively. Comparison of the experimental and theoretical master plots of various reaction mechanisms showed that when the conversion values are below 0.5, the most probable decomposition mechanism for HP and GO-HP is D1. Above 0.5, the decomposition mechanisms of HP and GO-HP are most probably described by A3 and R3 models, respectively. Take-Away: Graphene oxide (GO) doped hide powders (GO-HP) exhibit better thermal stability than those of raw hide powders. The activation energy values of GO-HP and raw hide powder were found to be 240.5 and 184.7 kJ/mol, respectively.

Related object and literature
urn:nbn:de:bsz:14-qucosa2-340872
qucosa:34087

Subject
Ingenieurwissenschaften

Event
Geistige Schöpfung
(who)
Luo, Lan
Zhang, Hao
Liu, Jie
Tang, Keyong
Event
Herstellung
(who)
International Union of Leather Technologists and Chemists Societies
Event
Veröffentlichung
(who)
Verein für Gerberei-Chemie und -Technik e. V.
Forschungsinstitut für Leder und Kunststoffbahnen (FILK) gGmbH

URN
urn:nbn:de:bsz:14-qucosa2-343162
Last update
14.03.2025, 8:16 AM CET

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Object type

  • Konferenzbeitrag

Associated

  • Luo, Lan
  • Zhang, Hao
  • Liu, Jie
  • Tang, Keyong
  • International Union of Leather Technologists and Chemists Societies
  • Verein für Gerberei-Chemie und -Technik e. V.
  • Forschungsinstitut für Leder und Kunststoffbahnen (FILK) gGmbH

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