Solid–Electrolyte Interphase at Positive Electrodes in High‐Energy Li‐Ion Batteries: Current Understanding and Analytical Tools
Abstract: Abstract: The operating potentials of the Li‐ion batteries active materials usually exceed the stability window of the electrolyte, leading to its irreversible reduction or oxidation. Often, as an effect of these side reactions, a surface layer is deposited onto the electrodes’ materials. These surface layers play a pivotal role on the battery performance, rate capability, irreversible charge losses, and safety. Despite their importance, such interphases are difficult to analyse because of their small thickness and sensitive chemical composition. With this review, the authors intend to describe the already established analytical tools for the analysis of the interphase layers formed at the electrodes’ surface in Li‐ion batteries, together with the novel, unconventional ones under current development, focusing on the strengths and weak points of each technique. Particular attention will be given to the surface layers formed onto the positive electrodes through a summary of their current understanding. This is of main importance since understanding the interphase at the positive electrode side could enable the next generation of high energy Li‐ion batteries.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Solid–Electrolyte Interphase at Positive Electrodes in High‐Energy Li‐Ion Batteries: Current Understanding and Analytical Tools ; volume:3 ; number:8 ; year:2020 ; pages:672-697 ; extent:26
Batteries & supercaps ; 3, Heft 8 (2020), 672-697 (gesamt 26)
- Creator
- DOI
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10.1002/batt.201900177
- URN
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urn:nbn:de:101:1-2022062412431229767846
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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15.08.2025, 7:27 AM CEST
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Associated
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Reactivity and compositional analysis of the solid electrolyte interphase and the cathode electrolyte interphase in different electrodes for Li-ion batteries
Designing the solid electrolyte interphase on silicon-based negative electrodes for high-energy density lithium ion batteries via tailored electrolyte additives
Nanoscale Morphological Characterization of Coordinated Binder and Solid Electrolyte Interphase in Silicon‐Based Electrodes for Li‐Ion Batteries
Critical Review on cathode–electrolyte Interphase Toward High-Voltage Cathodes for Li-Ion Batteries
Heterogeneous Solid Electrolyte Interphase Interactions Dictate Interface Instability in Sodium Metal Electrodes
Heterogeneous Solid‐Electrolyte Interphase in Graphite Electrodes Assessed by 4D‐Resolved Computational Simulations
In Situ Mechanical Analysis of the Nanoscopic Solid Electrolyte Interphase on Anodes of Li‐Ion Batteries
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Dynamics of Solid‐Electrolyte Interphase Formation on Silicon Electrodes Revealed by Combinatorial Electrochemical Screening
Transmission X-ray Absorption Spectroscopy of the Solid Electrolyte Interphase on Silicon Anodes for Li-ion Batteries
Model Studies on Solid Electrolyte Interphase Formation on Graphite Electrodes in Ethylene Carbonate and Dimethyl Carbonate II: Graphite Powder Electrodes
Impact of dual-layer solid-electrolyte interphase inhomogeneities on early-stage defect formation in Si electrodes
Reactivity and compositional analysis of the solid electrolyte interphase and the cathode electrolyte interphase in different electrodes for Li-ion batteries
Designing the solid electrolyte interphase on silicon-based negative electrodes for high-energy density lithium ion batteries via tailored electrolyte additives
Nanoscale Morphological Characterization of Coordinated Binder and Solid Electrolyte Interphase in Silicon‐Based Electrodes for Li‐Ion Batteries
Critical Review on cathode–electrolyte Interphase Toward High-Voltage Cathodes for Li-Ion Batteries
Heterogeneous Solid Electrolyte Interphase Interactions Dictate Interface Instability in Sodium Metal Electrodes
Heterogeneous Solid‐Electrolyte Interphase in Graphite Electrodes Assessed by 4D‐Resolved Computational Simulations
In Situ Mechanical Analysis of the Nanoscopic Solid Electrolyte Interphase on Anodes of Li‐Ion Batteries
Dynamics of Solid‐Electrolyte Interphase Formation on Silicon Electrodes Revealed by Combinatorial Electrochemical Screening
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