Bicyclo (2.1.1) hexanes via Intramolecular Formal (3+2)‐Cycloaddition
Abstract: We report a synthesis of bicyclo[2.1.1]hexanes via an intramolecular formal (3+2) cycloaddition of allylated cyclopropanes bearing a 4‐nitrobenzimine substituent. Both activated and unactivated alkenes are tolerated in the transformation. The bicyclic imine products are prone to photo‐induced ring opening, allowing for the epimerization of C5‐stereogenic compounds.
- Standort
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Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
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Online-Ressource
- Sprache
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Englisch
- Erschienen in
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Bicyclo (2.1.1) hexanes via Intramolecular Formal (3+2)‐Cycloaddition ; day:02 ; month:12 ; year:2024 ; extent:8
Angewandte Chemie / International edition. International edition ; (02.12.2024) (gesamt 8)
- Urheber
- DOI
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10.1002/anie.202413695
- URN
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urn:nbn:de:101:1-2412031314068.976468480552
- Rechteinformation
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
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15.08.2025, 07:31 MESZ
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Beteiligte
- Harmata, Alexander S.
- Tatunashvili, Elene
- Chang, Abigail
- Wang, Tao
- Stephenson, Corey R. J.
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