Increasing the Magnetic Blocking Temperature of Single‐Molecule Magnets

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Abstract: The synthesis of single‐molecule magnets (SMMs), magnetic complexes capable of retaining magnetization blocking for a long time at elevated temperatures, has been a major concern for magnetochemists over the last three decades. In this review, we describe basic SMMs and the different approaches that allow high magnetization‐blocking temperatures to be reached. We focus on the basic factors affecting magnetization blocking, magnetic axiality and the height of the blocking barrier, which can be used to group different families of complexes in terms of their SMM efficiency. Finally, we discuss several practical routes for the design of mono‐ and polynuclear complexes that could be applied in memory devices.

Standort
Deutsche Nationalbibliothek Frankfurt am Main
Umfang
Online-Ressource
Sprache
Englisch

Erschienen in
Increasing the Magnetic Blocking Temperature of Single‐Molecule Magnets ; day:29 ; month:09 ; year:2023 ; extent:20
Angewandte Chemie ; (29.09.2023) (gesamt 20)

Urheber
Vieru, Veacheslav
Gómez‐Coca, Silvia
Ruiz, Eliseo
Chibotaru, Liviu F.

DOI
10.1002/ange.202303146
URN
urn:nbn:de:101:1-2023092915270674442295
Rechteinformation
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Letzte Aktualisierung
14.08.2025, 10:57 MESZ

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Beteiligte

  • Vieru, Veacheslav
  • Gómez‐Coca, Silvia
  • Ruiz, Eliseo
  • Chibotaru, Liviu F.

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