Unlocking Mesoscopic Disorder in Graphitic Carbon with Spectroelectrochemistry
Abstract: Intrinsic structural and oxidic defects activate graphitic carbon electrodes towards electrochemical reactions underpinning energy conversion and storage technologies. Yet, these defects can also disrupt the long‐range and periodic arrangement of carbon atoms, thus, the characterization of graphitic carbon electrodes necessitates in‐situ atomistic differentiation of graphitic regions from mesoscopic bulk disorder. Here, we leverage the combined techniques of in‐situ attenuated total reflectance infrared spectroscopy and first‐principles calculations to reveal that graphitic carbon electrodes exhibit electric‐field dependent infrared activity that is sensitive to the bulk mesoscopic intrinsic disorder. With this platform, we identify graphitic regions from amorphous domains by discovering that they demonstrate opposing electric‐field‐dependent infrared activity under electrochemical conditions. Our work provides a roadmap for identifying mesoscopic disorder in bulk carbon materials under potential bias.
- Standort
-
Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
-
Online-Ressource
- Sprache
-
Englisch
- Erschienen in
-
Unlocking Mesoscopic Disorder in Graphitic Carbon with Spectroelectrochemistry ; day:16 ; month:01 ; year:2025 ; extent:9
Angewandte Chemie / International edition. International edition ; (16.01.2025) (gesamt 9)
- Urheber
-
Papadopoulos, Ry
Masters, Benjamin
Kundu, Arpan
Maldonado, Nicholas
Filatov, Alexander S.
Liu, Yuzi
Kim, Taemin
Galli, Giulia
Wuttig, Anna
- DOI
-
10.1002/anie.202420680
- URN
-
urn:nbn:de:101:1-2501171308130.043240167962
- Rechteinformation
-
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
- 15.08.2025, 07:37 MESZ
Datenpartner
Deutsche Nationalbibliothek. Bei Fragen zum Objekt wenden Sie sich bitte an den Datenpartner.
Beteiligte
- Papadopoulos, Ry
- Masters, Benjamin
- Kundu, Arpan
- Maldonado, Nicholas
- Filatov, Alexander S.
- Liu, Yuzi
- Kim, Taemin
- Galli, Giulia
- Wuttig, Anna
Ähnliche Objekte (12)
Unlocking Mesoscopic Disorder in Graphitic Carbon with Spectroelectrochemistry
Order−disorder interfaces in a graphitic carbon nitride-nanoclay composite for improved photodynamic antibiotics
Synthesis and characterization of aluminum-doped graphitic carbon
Utilization of graphitic carbon nitride in dispersed media
Desilylative or Decarboxylative Photoadditions with Graphitic Carbon Nitride
Exploring graphitic carbon nitrides for (opto)electronic applications
Graphitic Carbon Nitride Stabilized Water‐in‐Water Emulsions
Desorption of gases from graphitic and porous carbon surfaces
Graphitic carbon grown on fluorides by molecular beam epitaxy
Sub-millisecond lithiothermal synthesis of graphitic meso–microporous carbon
Fast hydrogen purification through graphitic carbon nitride nanosheet membranes
Mesoporous and Graphitic Carbide-Derived Carbon for Catalytic Applications
Unlocking Mesoscopic Disorder in Graphitic Carbon with Spectroelectrochemistry
Order−disorder interfaces in a graphitic carbon nitride-nanoclay composite for improved photodynamic antibiotics
Synthesis and characterization of aluminum-doped graphitic carbon
Utilization of graphitic carbon nitride in dispersed media
Desilylative or Decarboxylative Photoadditions with Graphitic Carbon Nitride
Exploring graphitic carbon nitrides for (opto)electronic applications
Graphitic Carbon Nitride Stabilized Water‐in‐Water Emulsions
Desorption of gases from graphitic and porous carbon surfaces
Graphitic carbon grown on fluorides by molecular beam epitaxy
Sub-millisecond lithiothermal synthesis of graphitic meso–microporous carbon
Fast hydrogen purification through graphitic carbon nitride nanosheet membranes
Mesoporous and Graphitic Carbide-Derived Carbon for Catalytic Applications
Unlocking Mesoscopic Disorder in Graphitic Carbon with Spectroelectrochemistry
Order−disorder interfaces in a graphitic carbon nitride-nanoclay composite for improved photodynamic antibiotics
Synthesis and characterization of aluminum-doped graphitic carbon
Utilization of graphitic carbon nitride in dispersed media
Desilylative or Decarboxylative Photoadditions with Graphitic Carbon Nitride
Exploring graphitic carbon nitrides for (opto)electronic applications
Graphitic Carbon Nitride Stabilized Water‐in‐Water Emulsions
Desorption of gases from graphitic and porous carbon surfaces
Graphitic carbon grown on fluorides by molecular beam epitaxy
Sub-millisecond lithiothermal synthesis of graphitic meso–microporous carbon
Fast hydrogen purification through graphitic carbon nitride nanosheet membranes