Carbonylation Reactions Using Single‐Atom Catalysts

Abstract: The development of highly efficient and selective catalysts for carbonylation reactions represents a significant challenge in catalysis. Single‐atom catalysts (SACs) have postulated as promising candidates able to combine the strengths of both homogeneous and heterogeneous catalysts. In this paper, we review recent advances in tailoring solid supports for SACs to enhance their catalytic performance in carbonylation reactions. We first discuss the effect of supports on the hydroformylation reaction catalysed by SACs, followed by recent advances for methanol, ethanol, and dimethyl ether carbonylation reactions, focusing on the design of halide‐free catalysts with improved activity and stability. Finally, oxidative carbonylation is discussed. Overall, this review highlights the importance of tailoring solid supports for SACs to achieve highly active and selective catalysts in carbonylation reactions, paving the way for future developments in sustainable catalysis.

Location
Deutsche Nationalbibliothek Frankfurt am Main
Extent
Online-Ressource
Language
Englisch

Bibliographic citation
Carbonylation Reactions Using Single‐Atom Catalysts ; day:17 ; month:07 ; year:2024 ; extent:30
ChemCatChem ; (17.07.2024) (gesamt 30)

Creator
Jurado, Lole
Posada‐Pérez, Sergio
Axet, M. Rosa

DOI
10.1002/cctc.202400543
URN
urn:nbn:de:101:1-2407181426481.736179491554
Rights
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Last update
14.08.2025, 8:46 AM UTC

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Associated

  • Jurado, Lole
  • Posada‐Pérez, Sergio
  • Axet, M. Rosa

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