Lewis Acid Promoted Dearomatization of Naphthols

Abstract: Two‐step dearomative functionalization of naphthols promoted by Lewis acids and copper (I) catalysis was developed. Initially, Lewis acid complexation inverted the electronic properties of the ring and established an equilibrium with the dearomatized counterpart. Subsequent trapping of the dearomatized intermediate with organometallics as well as organophosphines was demonstrated and provided the corresponding dearomatized products.

Location
Deutsche Nationalbibliothek Frankfurt am Main
Extent
Online-Ressource
Language
Englisch

Bibliographic citation
Lewis Acid Promoted Dearomatization of Naphthols ; volume:26 ; number:68 ; year:2020 ; pages:15843-15846 ; extent:4
Chemistry - a European journal ; 26, Heft 68 (2020), 15843-15846 (gesamt 4)

Creator
Kulish, Kirill
Boldrini, Cosimo
Castiñeira Reis, Marta
Pérez, Juana M.
Harutyunyan, Syuzanna R.

DOI
10.1002/chem.202003392
URN
urn:nbn:de:101:1-2022060520025244590310
Rights
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Last update
31.03.20242024, 5:21 PM CEST

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Associated

  • Kulish, Kirill
  • Boldrini, Cosimo
  • Castiñeira Reis, Marta
  • Pérez, Juana M.
  • Harutyunyan, Syuzanna R.

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