Visible‐Light Cascade Photooxygenation of Tetrahydrocarbazoles and Cyclohepta (b) indoles: Access to C, N ‐Diacyliminium Ions
Abstract: Tetrahydrocarbazoles and perhydrocyclohepta[b]indoles undergo a catalytic cascade singlet oxygenation in alkaline medium, which leads to chiral tricyclic perhydropyrido‐ and perhydroazepino[1,2‐a]indoles in a single operation. These photooxygenation products are new synthetic equivalents of uncommon C,N‐diacyliminium ions and can be functionalized with the aid of phosphoric acid organocatalysis.
- Standort
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Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
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Online-Ressource
- Sprache
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Englisch
- Erschienen in
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Visible‐Light Cascade Photooxygenation of Tetrahydrocarbazoles and Cyclohepta (b) indoles: Access to C, N ‐Diacyliminium Ions ; volume:132 ; number:30 ; year:2020 ; pages:12550-12554 ; extent:5
Angewandte Chemie ; 132, Heft 30 (2020), 12550-12554 (gesamt 5)
- Urheber
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Frahm, Mario
von Drathen, Thorsten
Gronbach, Lisa Marie
Voss, Alice
Lorenz, Felix
Bresien, Jonas
Villinger, Alexander
Hoffmann, Frank
Brasholz, Malte
- DOI
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10.1002/ange.202007549
- URN
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urn:nbn:de:101:1-2022053006551486881906
- Rechteinformation
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
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15.08.2025, 07:34 MESZ
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Beteiligte
- Frahm, Mario
- von Drathen, Thorsten
- Gronbach, Lisa Marie
- Voss, Alice
- Lorenz, Felix
- Bresien, Jonas
- Villinger, Alexander
- Hoffmann, Frank
- Brasholz, Malte
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