Heterostructured Electrocatalysts: from Fundamental Microkinetic Model to Electron Configuration and Interfacial Reactive Microenvironment
Abstract: Electrocatalysts can efficiently convert earth‐abundant simple molecules into high‐value‐added products. In this context, heterostructures, which are largely determined by the interface, have emerged as a pivotal architecture for enhancing the activity of electrocatalysts. In this review, the atomistic understanding of heterostructured electrocatalysts is considered, focusing on the reaction kinetic rate and electron configuration, gained from both empirical studies and theoretical models. We start from the fundamentals of the microkinetic model, adsorption energy theory, and electric double layer model. The importance of heterostructures to accelerate electrochemical processes via modulating electron configuration and interfacial reactive microenvironment is highlighted, by considering rectification, space charge region, built‐in electric field, synergistic interactions, lattice strain, and geometric effect. We conclude this review by summarizing the challenges and perspectives in the field of heterostructured electrocatalysts, such as the determination of transition state energy, their dynamic evolution, refinement of the theoretical approaches, and the use of machine learning.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Heterostructured Electrocatalysts: from Fundamental Microkinetic Model to Electron Configuration and Interfacial Reactive Microenvironment ; day:04 ; month:03 ; year:2025 ; extent:24
Advanced materials ; (04.03.2025) (gesamt 24)
- Creator
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Li, Yun
Hassan, Md. Samim
Zhao, Xin
Rogach, Andrey L.
- DOI
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10.1002/adma.202418146
- URN
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urn:nbn:de:101:1-2503051326570.085858444520
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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15.08.2025, 7:34 AM CEST
Data provider
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Associated
- Li, Yun
- Hassan, Md. Samim
- Zhao, Xin
- Rogach, Andrey L.
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