Understanding MOF Flexibility: An Analysis Focused on Pillared Layer MOFs as a Model System

Abstract: Flexible porous frameworks are at the forefront of materials research. A unique feature is their ability to open and close their pores in an adaptive manner induced by chemical and physical stimuli. Such enzyme‐like selective recognition offers a wide range of functions ranging from gas storage and separation to sensing, actuation, mechanical energy storage and catalysis. However, the factors affecting switchability are poorly understood. In particular, the role of building blocks, as well as secondary factors (crystal size, defects, cooperativity) and the role of host–guest interactions, profit from systematic investigations of an idealized model by advanced analytical techniques and simulations. The review describes an integrated approach targeting the deliberate design of pillared layer metal–organic frameworks as idealized model materials for the analysis of critical factors affecting framework dynamics and summarizes the resulting progress in their understanding and application.

Location
Deutsche Nationalbibliothek Frankfurt am Main
Extent
Online-Ressource
Language
Englisch

Bibliographic citation
Understanding MOF Flexibility: An Analysis Focused on Pillared Layer MOFs as a Model System ; day:11 ; month:05 ; year:2023 ; extent:48
Angewandte Chemie / International edition. International edition ; (11.05.2023) (gesamt 48)

Creator
Senkovska, Irena
Bon, Volodymyr
Abylgazina, Leila
Mendt, Matthias
Berger, Jan
Kieslich, Gregor
Petkov, Petko
Fiorio, Jhonatan L.
Joswig, Jan‐Ole
Heine, Thomas
Schaper, Larissa
Bachetzky, Christopher
Schmid, Rochus
Fischer, Roland A.
Pöppl, Andreas
Brunner, Eike
Kaskel, Stefan

DOI
10.1002/anie.202218076
URN
urn:nbn:de:101:1-2023051115440446068637
Rights
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Last update
14.08.2025, 11:03 AM CEST

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