Persistent and Predominantly Localized Boron Radical from the Reduction of a Three‐Dimensional Analogue of NHC‐Stabilized Borafluorenium
Abstract: In this contribution, we reported the three‐dimensional (3D) analogues of N‐heterocyclic carbene (NHC)‐stabilized 9‐borafluorenium and 9‐borafluorene radical. The radical was fully characterized by cyclic voltammetry (CV), UV‐Vis absorption spectroscopy, electron paramagnetic resonance (EPR) and single‐crystal X‐ray diffraction analyses. The distinct boron‐centered radical character of 9‐borafluorene radical was corroborated by DFT calculations and EPR analysis.
- Standort
-
Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
-
Online-Ressource
- Sprache
-
Englisch
- Erschienen in
-
Persistent and Predominantly Localized Boron Radical from the Reduction of a Three‐Dimensional Analogue of NHC‐Stabilized Borafluorenium ; day:24 ; month:05 ; year:2023 ; extent:7
Chemistry - a European journal ; (24.05.2023) (gesamt 7)
- Urheber
-
Xiang, Libo
Wang, Junyi
Krummenacher, Ivo
Radacki, Krzysztof
Braunschweig, Holger
Lin, Zhenyang
Ye, Qing
- DOI
-
10.1002/chem.202301270
- URN
-
urn:nbn:de:101:1-2023052515053443368953
- Rechteinformation
-
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
- 14.08.2025, 10:53 MESZ
Datenpartner
Dieses Objekt wird bereitgestellt von:
Deutsche Nationalbibliothek. Bei Fragen zum Objekt wenden Sie sich bitte an den Datenpartner.
Deutsche Nationalbibliothek. Bei Fragen zum Objekt wenden Sie sich bitte an den Datenpartner.
Beteiligte
- Xiang, Libo
- Wang, Junyi
- Krummenacher, Ivo
- Radacki, Krzysztof
- Braunschweig, Holger
- Lin, Zhenyang
- Ye, Qing
Ähnliche Objekte (12)
Gating of water channels (aquaporins) in plants : effects of osmotic and oxidative stresses and the role of unstirred layers
Cationic Nickel d 9 ‐Metalloradicals (Ni (NHC) 2) +
Borirenes and Boriranes: Development and Perspectives
Cationic Nickel d9‐Metalloradicals [Ni(NHC)2]+
A Three‐Dimensional Inorganic Analogue of 9,10‐Diazido‐9,10‐Diboraanthracene: A Lewis Superacidic Azido Borane with Reactivity and Stability
A Three‐Dimensional Inorganic Analogue of 9,10‐Diazido‐9,10‐Diboraanthracene: A Lewis Superacidic Azido Borane with Reactivity and Stability
Do independent directors play a political role? Evidence from independent directors' death events
The cross-section of stock returns in an early stock market
Small Responsible Innovators and Open Innovation towards Sustainability: Networks Conditions
A Three-Dimensional Inorganic Analogue of 9,10-Diazido-9,10-Diboraanthracene: A Lewis Superacidic Azido Borane with Reactivity and Stability
Rhodium‐Mediated Stoichiometric Synthesis of Mono‐, Bi‐, and Bis‐1,2‐Azaborinines: 1‐Rhoda‐3,2‐azaboroles as Reactive Precursors
Well‐Defined, Molecular Bismuth Compounds: Catalysts in Photochemically Induced Radical Dehydrocoupling Reactions
Gating of water channels (aquaporins) in plants : effects of osmotic and oxidative stresses and the role of unstirred layers
Cationic Nickel d 9 ‐Metalloradicals (Ni (NHC) 2) +
Borirenes and Boriranes: Development and Perspectives
Cationic Nickel d9‐Metalloradicals [Ni(NHC)2]+
A Three‐Dimensional Inorganic Analogue of 9,10‐Diazido‐9,10‐Diboraanthracene: A Lewis Superacidic Azido Borane with Reactivity and Stability
A Three‐Dimensional Inorganic Analogue of 9,10‐Diazido‐9,10‐Diboraanthracene: A Lewis Superacidic Azido Borane with Reactivity and Stability
Do independent directors play a political role? Evidence from independent directors' death events
The cross-section of stock returns in an early stock market
Small Responsible Innovators and Open Innovation towards Sustainability: Networks Conditions
A Three-Dimensional Inorganic Analogue of 9,10-Diazido-9,10-Diboraanthracene: A Lewis Superacidic Azido Borane with Reactivity and Stability
Rhodium‐Mediated Stoichiometric Synthesis of Mono‐, Bi‐, and Bis‐1,2‐Azaborinines: 1‐Rhoda‐3,2‐azaboroles as Reactive Precursors
Well‐Defined, Molecular Bismuth Compounds: Catalysts in Photochemically Induced Radical Dehydrocoupling Reactions
Gating of water channels (aquaporins) in plants : effects of osmotic and oxidative stresses and the role of unstirred layers
Cationic Nickel d 9 ‐Metalloradicals (Ni (NHC) 2) +
Borirenes and Boriranes: Development and Perspectives
Cationic Nickel d9‐Metalloradicals [Ni(NHC)2]+
A Three‐Dimensional Inorganic Analogue of 9,10‐Diazido‐9,10‐Diboraanthracene: A Lewis Superacidic Azido Borane with Reactivity and Stability
A Three‐Dimensional Inorganic Analogue of 9,10‐Diazido‐9,10‐Diboraanthracene: A Lewis Superacidic Azido Borane with Reactivity and Stability
Do independent directors play a political role? Evidence from independent directors' death events
The cross-section of stock returns in an early stock market
Small Responsible Innovators and Open Innovation towards Sustainability: Networks Conditions
A Three-Dimensional Inorganic Analogue of 9,10-Diazido-9,10-Diboraanthracene: A Lewis Superacidic Azido Borane with Reactivity and Stability
Rhodium‐Mediated Stoichiometric Synthesis of Mono‐, Bi‐, and Bis‐1,2‐Azaborinines: 1‐Rhoda‐3,2‐azaboroles as Reactive Precursors