Multifunctional Organometallic Compounds: An Interesting Luminescent NLO‐Active Alkynylplatinum (II) Complex
Abstract: Reaction of 4‐methylphenylacetylide with the known chlorido platinum (II) complex bearing the cyclometalated 1,3‐bis (pyridin‐2‐yl)‐4,6‐difluoro‐benzene ligand afforded a novel alkynyl platinum (II) complex, 1, that was fully characterized by elemental analysis, NMR and UV‐visible spectroscopies, by photoluminescence measurements, and by computational modelling. Its structure was determined by X‐ray diffraction studies on a single crystal whereas its second‐order nonlinear optical (NLO) properties were determined in solution by the Electric‐Field Induced Second Harmonic generation method. The novel multifunctional complex 1 is characterized by good luminescence properties, like the related chlorido Pt (II) complex, but by a much higher second‐order NLO response.
- Standort
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Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
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Online-Ressource
- Sprache
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Englisch
- Erschienen in
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Multifunctional Organometallic Compounds: An Interesting Luminescent NLO‐Active Alkynylplatinum (II) Complex ; day:07 ; month:11 ; year:2024 ; extent:8
European journal of inorganic chemistry ; (07.11.2024) (gesamt 8)
- Urheber
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Colombo, Alessia
Dragonetti, Claudia
Fagnani, Francesco
Roberto, Dominique
Guerchais, Véronique
Roisnel, Thierry
Fantacci, Simona
Marinotto, Daniele
- DOI
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10.1002/ejic.202400478
- URN
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urn:nbn:de:101:1-2411081406145.949600907229
- Rechteinformation
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
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15.08.2025, 07:24 MESZ
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Beteiligte
- Colombo, Alessia
- Dragonetti, Claudia
- Fagnani, Francesco
- Roberto, Dominique
- Guerchais, Véronique
- Roisnel, Thierry
- Fantacci, Simona
- Marinotto, Daniele
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