N‐Heterocyclic Carbene Acyl Anion Organocatalysis by Ball‐Milling
Abstract: The ability to conduct N‐heterocyclic carbene‐catalysed acyl anion chemistry under ball‐milling conditions is reported for the first time. This process has been exemplified through applications to intermolecular‐benzoin, intramolecular‐benzoin, intermolecular‐Stetter and intramolecular‐Stetter reactions including asymmetric examples and demonstrates that this mode of mechanistically complex organocatalytic reaction can operate under solvent‐minimised conditions.
- Standort
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Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
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Online-Ressource
- Sprache
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Englisch
- Erschienen in
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N‐Heterocyclic Carbene Acyl Anion Organocatalysis by Ball‐Milling ; volume:13 ; number:1 ; year:2020 ; pages:131-135 ; extent:5
ChemSusChem ; 13, Heft 1 (2020), 131-135 (gesamt 5)
- Urheber
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Nicholson, William I.
Seastram, Alex C.
Iqbal, Saqib A.
Reed‐Berendt, Benjamin G.
Morrill, Louis C.
Browne, Duncan L.
- DOI
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10.1002/cssc.201902346
- URN
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urn:nbn:de:101:1-2022060907393759350935
- Rechteinformation
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
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15.08.2025, 07:24 MESZ
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Beteiligte
- Nicholson, William I.
- Seastram, Alex C.
- Iqbal, Saqib A.
- Reed‐Berendt, Benjamin G.
- Morrill, Louis C.
- Browne, Duncan L.
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