Single Crystals of Insoluble Porous Salicylimine Cages

Abstract: Porous organic cages (POCs) are meanwhile an established class of porous materials. Most of them are soluble to a certain extend and thus processable in or from solution. However, a few of larger salicylimine cages were reported to be insoluble in any organic solvents and thus characterized as amorphous materials. These cages were now synthesized as single‐crystalline materials to get insight into packing motifs and preferred intermolecular interactions. Furthermore, the pairs of crystalline and amorphous materials for each cage allowed to compare their gas‐sorption properties in both morphological states.

Object Details

• Location: Deutsche Nationalbibliothek Frankfurt am Main
• Extent: Online-Ressource
• Language: Englisch

References and Relationships

• Bibliographic citation: Single Crystals of Insoluble Porous Salicylimine Cages ; day:16 ; month:10 ; year:2023 ; extent:11 ; Chemistry - a European journal ; (16.10.2023) (gesamt 11)

Contributors, Places and Time

• Creator: Holsten, Mattes ; Elbert, Sven ; Rominger, Frank ; Zhang, Wen‐Shan ; Schröder, Rasmus R. ; Mastalerz, Michael

Further information

• DOI: 10.1002/chem.202302116
• URN: urn:nbn:de:101:1-2023101715103941820687
• Rights: Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
• Last update: 14.08.2025, 10:46 AM CEST