A Comparison of Phenolic Monomers Produced from Different Types of Lignin by Phosphotungstic Acid Catalysts

Abstract: Herein we studied the chemical structure of different types of lignin samples and the potential to prepare phenolic monomers was illustrated by phosphotungstic acid catalysts. Different types of H/G/S lignin components had different structures. The lignin extracted from poplar had the highest molecular weight and β‐O‐4 aryl ether contents, followed by pine and straw lignin samples. After depolymerization by PTA catalyst, the yields of phenolic monomers detected was 8.06 wt % (poplar), 5.44 wt % (pine) and 4.52 wt % (straw), respectively. Further, the ratios of H/G/S in the phenol monomers were also different, indicating that the S, G and H types structural units were continuously transformed with each other during the reaction. In our study, the change in the types of lignin samples resulted into an improvement of the distribution of phenolic products, and also the selectivity of phenolic monomers significantly.

Standort
Deutsche Nationalbibliothek Frankfurt am Main
Umfang
Online-Ressource
Sprache
Englisch

Erschienen in
A Comparison of Phenolic Monomers Produced from Different Types of Lignin by Phosphotungstic Acid Catalysts ; volume:8 ; number:5 ; year:2019 ; pages:643-649 ; extent:7
ChemistryOpen ; 8, Heft 5 (2019), 643-649 (gesamt 7)

Urheber
Du, Boyu
Liu, Bingyang
Wang, Xing
Zhou, Jinghui

DOI
10.1002/open.201900088
URN
urn:nbn:de:101:1-2022080905383376645438
Rechteinformation
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Letzte Aktualisierung
01.08.2025, 07:21 MESZ

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Beteiligte

  • Du, Boyu
  • Liu, Bingyang
  • Wang, Xing
  • Zhou, Jinghui

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