2D Layered Nanomaterials as Fillers in Polymer Composite Electrolytes for Lithium Batteries

Abstract: Polymer composite electrolytes (PCEs), i.e., materials combining the disciplines of polymer chemistry, inorganic chemistry, and electrochemistry, have received tremendous attention within academia and industry for lithium‐based battery applications. While PCEs often comprise 3D micro‐ or nanoparticles, this review thoroughly summarizes the prospects of 2D layered inorganic, organic, and hybrid nanomaterials as active (ion conductive) or passive (nonion conductive) fillers in PCEs. The synthetic inorganic nanofillers covered here include graphene oxide, boron nitride, transition metal chalcogenides, phosphorene, and MXenes. Furthermore, the use of naturally occurring 2D layered clay minerals, such as layered double hydroxides and silicates, in PCEs is also thoroughly detailed considering their impact on battery cell performance. Despite the dominance of 2D layered inorganic materials, their organic and hybrid counterparts, such as 2D covalent organic frameworks and 2D metal–organic frameworks are also identified as tuneable nanofillers for use in PCE. Hence, this review gives an overview of the plethora of options available for the selective development of both the 2D layered nanofillers and resulting PCEs, which can revolutionize the field of polymer‐based solid‐state electrolytes and their implementation in lithium and post‐lithium batteries.

Location
Deutsche Nationalbibliothek Frankfurt am Main
Extent
Online-Ressource
Language
Englisch

Bibliographic citation
2D Layered Nanomaterials as Fillers in Polymer Composite Electrolytes for Lithium Batteries ; day:11 ; month:03 ; year:2023 ; extent:46
Advanced energy materials ; (11.03.2023) (gesamt 46)

Creator
Vijayakumar, Vidyanand
Ghosh, Meena
Asokan, Kiran
Sukumaran, Santhosh Babu
Kurungot, Sreekumar
Mindemark, Jonas
Brandell, Daniel
Winter, Martin
Nair, Jijeesh Ravi

DOI
10.1002/aenm.202203326
URN
urn:nbn:de:101:1-2023031114403249643103
Rights
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Last update
14.08.2025, 11:00 AM CEST

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Associated

  • Vijayakumar, Vidyanand
  • Ghosh, Meena
  • Asokan, Kiran
  • Sukumaran, Santhosh Babu
  • Kurungot, Sreekumar
  • Mindemark, Jonas
  • Brandell, Daniel
  • Winter, Martin
  • Nair, Jijeesh Ravi

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