Double Porphyrin Cage Compounds
The synthesis and characterization of double porphyrin cage compounds are described. They consist of two porphyrins that are each attached to a diphenylglycoluril‐based clip molecule via four ethyleneoxy spacers, and are linked together by a single alkyl chain using “click”‐chemistry. Following a newly developed multistep synthesis procedure we report three of these double porphyrin cages, linked by spacers of different lengths, i.e. 3, 5, and 11 carbon atoms. The structures of the double porphyrin cages were fully characterized by NMR, which revealed that they consist of mixtures of two diastereoisomers. Their zinc derivatives are capable of forming sandwich‐like complexes with the ditopic ligand 1,4‐diazabicyclo[2,2,2]octane (dabco).
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Double Porphyrin Cage Compounds ; volume:2020 ; number:45 ; year:2020 ; pages:7087-7100 ; extent:14
European journal of organic chemistry ; 2020, Heft 45 (2020), 7087-7100 (gesamt 14)
- Creator
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Stout, Kathleen
Peters, Theo P. J.
Mabesoone, Mathijs F. J.
Visschers, Fabian L. L.
Meijer, Eline M.
Klop, Joëlle‐Rose
van den Berg, Jeroen
White, Paul B.
Rowan, Alan E.
Nolte, Roeland J. M.
Elemans, Johannes A. A. W.
- DOI
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10.1002/ejoc.202001211
- URN
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urn:nbn:de:101:1-2022062308423486367835
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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15.08.2025, 7:34 AM CEST
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Associated
- Stout, Kathleen
- Peters, Theo P. J.
- Mabesoone, Mathijs F. J.
- Visschers, Fabian L. L.
- Meijer, Eline M.
- Klop, Joëlle‐Rose
- van den Berg, Jeroen
- White, Paul B.
- Rowan, Alan E.
- Nolte, Roeland J. M.
- Elemans, Johannes A. A. W.
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Allosteric Guest Binding in Chiral Zirconium(IV) Double Decker Porphyrin Cages
113 Cd as a Probe in NMR Studies of Allosteric Host‐Guest‐Ligand Complexes of Porphyrin Cage Compounds
Carbocyclic cage compounds : chemistry and applications
Syntheses and studies on non-covalent interactions of porphyrin compounds
Host‐guest tuning of the CO 2 reduction activity of an iron porphyrin cage
A Novel M 8 L 6 Cubic Cage That Binds Tetrapyridyl Porphyrins: Cage and Solvent Effects in Cobalt‐Porphyrin‐Catalyzed Cyclopropanation Reactions
Tuning the Porphyrin Building Block in Self‐Assembled Cages for Branched‐Selective Hydroformylation of Propene
Photocatalytic Hydrogen Evolution by a Synthetic (FeFe) Hydrogenase Mimic Encapsulated in a Porphyrin Cage
Isoreticular Crystallization of Highly Porous Cubic Covalent Organic Cage Compounds **
Isoreticular crystallization of highly porous cubic covalent organic cage compounds
Cage in Cage
Light‐gated binding in double‐motorized porphyrin cages
Allosteric Guest Binding in Chiral Zirconium(IV) Double Decker Porphyrin Cages
113 Cd as a Probe in NMR Studies of Allosteric Host‐Guest‐Ligand Complexes of Porphyrin Cage Compounds
Carbocyclic cage compounds : chemistry and applications
Syntheses and studies on non-covalent interactions of porphyrin compounds
Host‐guest tuning of the CO 2 reduction activity of an iron porphyrin cage
A Novel M 8 L 6 Cubic Cage That Binds Tetrapyridyl Porphyrins: Cage and Solvent Effects in Cobalt‐Porphyrin‐Catalyzed Cyclopropanation Reactions
Tuning the Porphyrin Building Block in Self‐Assembled Cages for Branched‐Selective Hydroformylation of Propene
Photocatalytic Hydrogen Evolution by a Synthetic (FeFe) Hydrogenase Mimic Encapsulated in a Porphyrin Cage
Isoreticular Crystallization of Highly Porous Cubic Covalent Organic Cage Compounds **
Isoreticular crystallization of highly porous cubic covalent organic cage compounds