Perfluoroalkylated Sulfoximines as Analogues of Togni Reagents: The Crucial Role of Fluorine Atoms for the Stability of Hypervalent Iodine Scaffolds

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Abstract: Hypervalent iodine compounds are described with perfluoroalkyl chains and S‐perfluoromethyl sulfoximines as ligands of the halogen. The influence of these groups on the stability of the cyclic structure is studied. The crucial role of the trifluoromethyl chain is clearly highlighted as an efficient ligand for the hypervalency. The structure and the reactivity of the new skeletons are discussed in detail.

Standort
Deutsche Nationalbibliothek Frankfurt am Main
Umfang
Online-Ressource
Sprache
Englisch

Erschienen in
Perfluoroalkylated Sulfoximines as Analogues of Togni Reagents: The Crucial Role of Fluorine Atoms for the Stability of Hypervalent Iodine Scaffolds ; day:22 ; month:11 ; year:2023 ; extent:8
European journal of organic chemistry ; (22.11.2023) (gesamt 8)

Urheber
Duhail, Thibaut
Kalim, Jorna
Marrot, Jérôme
Pégot, Bruce
Magnier, Emmanuel
Anselmi, Elsa

DOI
10.1002/ejoc.202300963
URN
urn:nbn:de:101:1-2023112314142720648163
Rechteinformation
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Letzte Aktualisierung
15.08.2025, 07:32 MESZ

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Beteiligte

  • Duhail, Thibaut
  • Kalim, Jorna
  • Marrot, Jérôme
  • Pégot, Bruce
  • Magnier, Emmanuel
  • Anselmi, Elsa

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