Recyclable Ruthenium Catalyst for Distal meta ‐C−H Activation
Abstract: We disclose the unprecedented hybrid‐ruthenium catalysis for distal meta‐C−H activation. The hybrid‐ruthenium catalyst was recyclable, as was proven by various heterogeneity tests, and fully characterized with various microscopic and spectroscopic techniques, highlighting the physical and chemical stability. Thereby, the hybrid‐ruthenium catalysis proved broadly applicable for meta‐C−H alkylations of among others purine‐based nucleosides and natural product conjugates. Additionally, its versatility was further reflected by meta‐C−H activations through visible‐light irradiation, as well as para‐selective C−H activations.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Recyclable Ruthenium Catalyst for Distal meta ‐C−H Activation ; volume:26 ; number:66 ; year:2020 ; pages:15290-15297 ; extent:8
Chemistry - a European journal ; 26, Heft 66 (2020), 15290-15297 (gesamt 8)
- Creator
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Choi, Isaac
Müller, Valentin
Wang, Yanhui
Xue, Kai
Kuniyil, Rositha
Andreas, Loren B.
Karius, Volker
Alauzun, Johan G.
Ackermann, Lutz
- DOI
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10.1002/chem.202003622
- URN
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urn:nbn:de:101:1-2022060411213116813362
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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15.08.2025, 7:34 AM CEST
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Associated
- Choi, Isaac
- Müller, Valentin
- Wang, Yanhui
- Xue, Kai
- Kuniyil, Rositha
- Andreas, Loren B.
- Karius, Volker
- Alauzun, Johan G.
- Ackermann, Lutz
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Insights into Ruthenium (II/IV)‐Catalyzed Distal C−H Oxygenation by Weak Coordination
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Carboxylate-Assisted Ruthenium-Catalyzed Direct C-H Bond Functionalizations
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Ruthenium(II)- and Copper(I)-Catalyzed C–H Functionalizations
Ruthenium- and Cobalt-Catalyzed Chelation-Assisted C–H Functionalization
Ergebnisse der Kniegelenkssynovektomie bei juveniler chronischer Arthritis
Photoinduzierte Ruthenium‐katalysierte C−H Arylierungspolymerisation bei Raumtemperatur
C7‐Indole Amidations and Alkenylations by Ruthenium (II) Catalysis
C7‐Indol‐Amidierung und ‐Alkenylierung durch Ruthenium (II)‐ Katalyse
Photo‐Induced Ruthenium‐Catalyzed C−H Arylation Polymerization at Ambient Temperature
Insights into Ruthenium (II/IV)‐Catalyzed Distal C−H Oxygenation by Weak Coordination
Ruthenium- and Cobalt-Catalyzed C-H Activation
Ruthenium(II)-Catalyzed C-H Arylations of Arenes
Carboxylate-Assisted Ruthenium-Catalyzed Direct C-H Bond Functionalizations
Ruthenium‐Catalyzed Aminocarbonylation with Isocyanates Through Weak Coordinating Groups
Ruthenium(II)- and Copper(I)-Catalyzed C–H Functionalizations
Ruthenium- and Cobalt-Catalyzed Chelation-Assisted C–H Functionalization
Ergebnisse der Kniegelenkssynovektomie bei juveniler chronischer Arthritis
Photoinduzierte Ruthenium‐katalysierte C−H Arylierungspolymerisation bei Raumtemperatur
C7‐Indole Amidations and Alkenylations by Ruthenium (II) Catalysis
C7‐Indol‐Amidierung und ‐Alkenylierung durch Ruthenium (II)‐ Katalyse
Photo‐Induced Ruthenium‐Catalyzed C−H Arylation Polymerization at Ambient Temperature
Insights into Ruthenium (II/IV)‐Catalyzed Distal C−H Oxygenation by Weak Coordination
Ruthenium- and Cobalt-Catalyzed C-H Activation
Ruthenium(II)-Catalyzed C-H Arylations of Arenes
Carboxylate-Assisted Ruthenium-Catalyzed Direct C-H Bond Functionalizations
Ruthenium‐Catalyzed Aminocarbonylation with Isocyanates Through Weak Coordinating Groups
Ruthenium(II)- and Copper(I)-Catalyzed C–H Functionalizations