Facile Synthesis of Uranium Complexes with a Pendant Borane Lewis Acid and 1,2‐Insertion of CO into a U−N Bond
Abstract: In this contribution, we illustrate uranium complexes bearing a pendant borate (i.e. 1 and 2) or a pendant borane (i.e. 3 and 4) moiety via reaction of the highly strained uranacycle I with various 3‐coordinate boranes. Complexes 3 and 4 represent the first examples of uranium complexes with a pendant borane Lewis acid. Moreover, complex 3 was capable of activation of CO, delivering a new CO activation mode, and an abnormal CO 1,2‐insertion pathway into a U−N bond. The importance of the pendant borane moiety was confirmed by the controlled experiments.
- Location
-
Deutsche Nationalbibliothek Frankfurt am Main
- Extent
-
Online-Ressource
- Language
-
Englisch
- Bibliographic citation
-
Facile Synthesis of Uranium Complexes with a Pendant Borane Lewis Acid and 1,2‐Insertion of CO into a U−N Bond ; day:17 ; month:11 ; year:2022 ; extent:1
Angewandte Chemie / International edition. International edition ; (17.11.2022) (gesamt 1)
- Creator
- DOI
-
10.1002/anie.202212823
- URN
-
urn:nbn:de:101:1-2022111714254554993764
- Rights
-
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
-
15.08.2025, 7:27 AM CEST
Data provider
This object is provided by:
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Associated
- Su, Wei
- Rajeshkumar, Thayalan
- Xiang, Libo
- Maron, Laurent
- Ye, Qing
Other Objects (12)
Facile Synthesis of Uranium Complexes with a Pendant Borane Lewis Acid and 1,2‐Insertion of CO into a U−N Bond
Facile Synthesis of Uranium Complexes with a Pendant Borane Lewis Acid and 1,2‐Insertion of CO into a U−N Bond
Isolation of a Uranium(III)‐Carbon Multiple Bond Complex
Gating of water channels (aquaporins) in plants : effects of osmotic and oxidative stresses and the role of unstirred layers
Probing loop effects in wrong-sign Yukawa coupling region of Type-II 2HDM
Borirenes and Boriranes: Development and Perspectives
A Three‐Dimensional Inorganic Analogue of 9,10‐Diazido‐9,10‐Diboraanthracene: A Lewis Superacidic Azido Borane with Reactivity and Stability
A Three‐Dimensional Inorganic Analogue of 9,10‐Diazido‐9,10‐Diboraanthracene: A Lewis Superacidic Azido Borane with Reactivity and Stability
A Three-Dimensional Inorganic Analogue of 9,10-Diazido-9,10-Diboraanthracene: A Lewis Superacidic Azido Borane with Reactivity and Stability
Numerical analysis of vibration response of elastic tube bundle of heat exchanger based on fluid structure coupling analysis
A 1 km soil organic carbon density dataset with depth of 20cm and 100cm from 1985 to 2020 in China
Influence of recycled clay brick aggregate on the mechanical properties of concrete
Facile Synthesis of Uranium Complexes with a Pendant Borane Lewis Acid and 1,2‐Insertion of CO into a U−N Bond
Facile Synthesis of Uranium Complexes with a Pendant Borane Lewis Acid and 1,2‐Insertion of CO into a U−N Bond
Isolation of a Uranium(III)‐Carbon Multiple Bond Complex
Gating of water channels (aquaporins) in plants : effects of osmotic and oxidative stresses and the role of unstirred layers
Probing loop effects in wrong-sign Yukawa coupling region of Type-II 2HDM
Borirenes and Boriranes: Development and Perspectives
A Three‐Dimensional Inorganic Analogue of 9,10‐Diazido‐9,10‐Diboraanthracene: A Lewis Superacidic Azido Borane with Reactivity and Stability
A Three‐Dimensional Inorganic Analogue of 9,10‐Diazido‐9,10‐Diboraanthracene: A Lewis Superacidic Azido Borane with Reactivity and Stability
A Three-Dimensional Inorganic Analogue of 9,10-Diazido-9,10-Diboraanthracene: A Lewis Superacidic Azido Borane with Reactivity and Stability
Numerical analysis of vibration response of elastic tube bundle of heat exchanger based on fluid structure coupling analysis
A 1 km soil organic carbon density dataset with depth of 20cm and 100cm from 1985 to 2020 in China
Influence of recycled clay brick aggregate on the mechanical properties of concrete
Facile Synthesis of Uranium Complexes with a Pendant Borane Lewis Acid and 1,2‐Insertion of CO into a U−N Bond
Facile Synthesis of Uranium Complexes with a Pendant Borane Lewis Acid and 1,2‐Insertion of CO into a U−N Bond
Isolation of a Uranium(III)‐Carbon Multiple Bond Complex
Gating of water channels (aquaporins) in plants : effects of osmotic and oxidative stresses and the role of unstirred layers
Probing loop effects in wrong-sign Yukawa coupling region of Type-II 2HDM
Borirenes and Boriranes: Development and Perspectives
A Three‐Dimensional Inorganic Analogue of 9,10‐Diazido‐9,10‐Diboraanthracene: A Lewis Superacidic Azido Borane with Reactivity and Stability
A Three‐Dimensional Inorganic Analogue of 9,10‐Diazido‐9,10‐Diboraanthracene: A Lewis Superacidic Azido Borane with Reactivity and Stability
A Three-Dimensional Inorganic Analogue of 9,10-Diazido-9,10-Diboraanthracene: A Lewis Superacidic Azido Borane with Reactivity and Stability
Numerical analysis of vibration response of elastic tube bundle of heat exchanger based on fluid structure coupling analysis
A 1 km soil organic carbon density dataset with depth of 20cm and 100cm from 1985 to 2020 in China