Copper-Templated Formation of Dihelical Oligothiophene–Phenanthroline Assemblies
Abstract: We report the synthesis and comprehensive characterization of a series of (oligo) thiophene-bridged (bis) phenanthroline ligands. The complexation behavior of the ditopic ligands with Cu (I) was explored by high-resolution ESI mass spectrometry, UV-vis spectroscopy, and electrochemistry. Whereas ligands, in which the phenanthrolines are bridged by smaller (oligo) thiophene units, provided mainly mononuclear complexes, quaterthiophene-based ditopic ligands show a strong tendency to undergo metal-templated self-assembly into double-stranded, dinuclear helicates.
- Location
-
Deutsche Nationalbibliothek Frankfurt am Main
- Extent
-
Online-Ressource
- Language
-
Englisch
- Bibliographic citation
-
Copper-Templated Formation of Dihelical Oligothiophene–Phenanthroline Assemblies ; volume:4 ; number:03 ; year:2022 ; pages:86-101
Organic materials ; 4, Heft 03 (2022), 86-101
- Contributor
-
Schmid, Sylvia
Wunderlin, Markus
Mena-Osteritz, Elena
Bäuerle, Peter
- DOI
-
10.1055/a-1910-9165
- URN
-
urn:nbn:de:101:1-2022112411304689202478
- Rights
-
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
-
15.08.2025, 7:20 AM CEST
Data provider
This object is provided by:
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Deutsche Nationalbibliothek. If you have any questions about the object, please contact the data provider.
Associated
- Schmid, Sylvia
- Wunderlin, Markus
- Mena-Osteritz, Elena
- Bäuerle, Peter
Other Objects (12)
Copper-templated formation of dihelical oligothiophene-phenanthroline assemblies
Sculpting light using DNA origami-templated nanoparticle assemblies
From Interaction to Function in DNA‐Templated Supramolecular Self‐Assemblies
A Heterogenized Copper Phenanthroline System to Catalyze the Oxygen Reduction Reaction
Exploring structure-property-relationships in tailored heteroleptic phenanthroline-based copper(I) photosensitizers
Phenanthroline-based copper complexes for water splitting applications : photo-physical and spectroscopic investigations
RNA‐Templated Peptide Bond Formation Promotes L‐Homochirality
Protein-templated copper nanoclusters for fluorimetric determination of human serum albumin
Whisker Formation on SAC305 Soldered Assemblies
Konkave 1,10-Phenanthroline
Bright or Dark: Unexpected Photocatalytic Behavior of Closely Related Phenanthroline‐based Copper(I) Photosensitizers
Bright or Dark: Unexpected Photocatalytic Behavior of Closely Related Phenanthroline‐based Copper (I) Photosensitizers
Copper-templated formation of dihelical oligothiophene-phenanthroline assemblies
Sculpting light using DNA origami-templated nanoparticle assemblies
From Interaction to Function in DNA‐Templated Supramolecular Self‐Assemblies
A Heterogenized Copper Phenanthroline System to Catalyze the Oxygen Reduction Reaction
Exploring structure-property-relationships in tailored heteroleptic phenanthroline-based copper(I) photosensitizers
Phenanthroline-based copper complexes for water splitting applications : photo-physical and spectroscopic investigations
RNA‐Templated Peptide Bond Formation Promotes L‐Homochirality
Protein-templated copper nanoclusters for fluorimetric determination of human serum albumin
Whisker Formation on SAC305 Soldered Assemblies
Konkave 1,10-Phenanthroline
Bright or Dark: Unexpected Photocatalytic Behavior of Closely Related Phenanthroline‐based Copper(I) Photosensitizers
Bright or Dark: Unexpected Photocatalytic Behavior of Closely Related Phenanthroline‐based Copper (I) Photosensitizers
Copper-templated formation of dihelical oligothiophene-phenanthroline assemblies
Sculpting light using DNA origami-templated nanoparticle assemblies
From Interaction to Function in DNA‐Templated Supramolecular Self‐Assemblies
A Heterogenized Copper Phenanthroline System to Catalyze the Oxygen Reduction Reaction
Exploring structure-property-relationships in tailored heteroleptic phenanthroline-based copper(I) photosensitizers
Phenanthroline-based copper complexes for water splitting applications : photo-physical and spectroscopic investigations
RNA‐Templated Peptide Bond Formation Promotes L‐Homochirality
Protein-templated copper nanoclusters for fluorimetric determination of human serum albumin
Whisker Formation on SAC305 Soldered Assemblies
Konkave 1,10-Phenanthroline
Bright or Dark: Unexpected Photocatalytic Behavior of Closely Related Phenanthroline‐based Copper(I) Photosensitizers