Dithienophosphole‐Based Phosphinamides with Intriguing Self‐Assembly Behavior
Abstract: A new, highly adaptable type of phosphinamide‐based hydrogen bonding is representatively demonstrated in π‐conjugated phosphole materials. The rotational flexibility of these intermolecular P=O−H−N hydrogen bonds is demonstrated by X‐ray crystallography and variable‐concentration NMR spectroscopy. In addition to crystalline compounds, phosphinamide hydrogen bonding was successfully introduced into the self‐assembly of soft crystals, liquid crystals, and organogels, thus highlighting the high general value of this type of interaction for the formation of organic soft materials.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Dithienophosphole‐Based Phosphinamides with Intriguing Self‐Assembly Behavior ; volume:128 ; number:10 ; year:2016 ; pages:3542-3546 ; extent:5
Angewandte Chemie ; 128, Heft 10 (2016), 3542-3546 (gesamt 5)
- Creator
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Wang, Zisu
Gelfand, Benjamin S.
Baumgartner, Thomas
- DOI
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10.1002/ange.201511171
- URN
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urn:nbn:de:101:1-2022101009044641822902
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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15.08.2025, 7:32 AM CEST
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Associated
- Wang, Zisu
- Gelfand, Benjamin S.
- Baumgartner, Thomas
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Self-assembly behavior in hydrophilic block copolymers
Supramolecular self-assembly
Modeling through self-assembly
Macroscopic magnetic self-assembly
Gravity enables self‐assembly
Shape-assisted self-assembly
Self‐Assembly Behavior of Oppositely Charged Inverse Bipatchy Microcolloids
Self-replication via tile self-assembly
Preparation and self-assembly behavior of anisotropic polymer patchy particles
Control of nanoparticle self-assembly
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Dithienophosphole‐Based Phosphinamides with Intriguing Self‐Assembly Behavior
Self-assembly behavior in hydrophilic block copolymers
Supramolecular self-assembly
Modeling through self-assembly
Macroscopic magnetic self-assembly
Gravity enables self‐assembly
Shape-assisted self-assembly
Self‐Assembly Behavior of Oppositely Charged Inverse Bipatchy Microcolloids
Self-replication via tile self-assembly
Preparation and self-assembly behavior of anisotropic polymer patchy particles
Control of nanoparticle self-assembly