Phenothiazine‐functionalized poly(norbornene)s as high‐rate cathode‐materials for organic batteries
Abstract: Organic cathode materials are handled as promising candidates for new energy‐storage solutions based on their transition‐metal‐free composition. Phenothiazine‐based polymers are attractive owing to their redox potential of 3.5 V vs. Li/Li+ and high cycling stabilities. Herein, three types of poly(norbornene)s were investigated, functionalized with phenothiazine units through either a direct connection or ester linkages, as well as their crosslinked derivatives. The directly linked poly(3‐norbornylphenothiazine)s demonstrated excellent rate capability and cycling stability with a capacity retention of 73 % after 10 000 cycles at a C‐rate of 100 C for the crosslinked polymer. The polymer network structure of the crosslinked poly(3‐norbornylphenothiazine) was beneficial for its rate performance
- Standort
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Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
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Online-Ressource
- Sprache
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Englisch
- Anmerkungen
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ChemSusChem. - 13, 9 (2020) , 2232-2238, ISSN: 1864-564X
- Schlagwort
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Phenothiazin
- Ereignis
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Veröffentlichung
- (wo)
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Freiburg
- (wer)
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Universität
- (wann)
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2020
- DOI
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10.1002/cssc.201903168
- URN
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urn:nbn:de:bsz:25-freidok-1519877
- Rechteinformation
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Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
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25.03.2025, 13:43 MEZ
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Beteiligte
Entstanden
- 2020
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