Heterobifunctional Rotaxanes for Asymmetric Catalysis
Abstract: Heterobifunctional rotaxanes serve as efficient catalysts for the addition of malonates to Michael acceptors. We report a series of four different heterobifunctional rotaxanes, featuring an amine‐based thread and a chiral 1,1′‐binaphthyl‐phosphoric‐acid‐based macrocycle. High‐level DFT calculations provided mechanistic insights and enabled rational catalyst improvements, leading to interlocked catalysts that surpass their non‐interlocked counterparts in terms of reaction rates and stereoselectivities.
- Standort
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Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
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Online-Ressource
- Sprache
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Englisch
- Erschienen in
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Heterobifunctional Rotaxanes for Asymmetric Catalysis ; volume:59 ; number:13 ; year:2020 ; pages:5102-5107 ; extent:6
Angewandte Chemie / International edition. International edition ; 59, Heft 13 (2020), 5102-5107 (gesamt 6)
- Urheber
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Pairault, Noël
Zhu, Hui
Jansen, Dennis
Huber, Alexander
Daniliuc, Constantin Gabriel
Grimme, Stefan
Niemeyer, Jochen
- DOI
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10.1002/anie.201913781
- URN
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urn:nbn:de:101:1-2022061112093829320618
- Rechteinformation
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
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15.08.2025, 07:29 MESZ
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Beteiligte
- Pairault, Noël
- Zhu, Hui
- Jansen, Dennis
- Huber, Alexander
- Daniliuc, Constantin Gabriel
- Grimme, Stefan
- Niemeyer, Jochen
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