Janus Reactivity of Crownphyrinoids: Alkali‐ vs. Transition Metal‐Mediated Transformations of Crown Ether‐Porphyrin Hybrids

Abstract: Crownphyrinogens and crownphyrins constitute a group of macrocycles that combine the structural facets of porphyrinoids and crown ethers. The dual‐nature cavity embedded in their molecules enables reactivity involving two structurally distinct parts of the macrocyclic ligand. Upon Ni (II) and Pd (II) insertion, coordination compounds are produced wherein the metal is incorporated into the porphyrinoid‐like pocket, resulting in monomeric or accordion‐like dimeric products, depending on the oxidation level of the macrocycle and metal cation. The reactions with Na (I) and K (I) resulted in the formation of complexes where only the crown ether segment of the molecule is involved in metal binding, yielding remarkable dimeric species. The exploitation of a crownphyrin large enough to accommodate two metal cations allowed the synthesis of an alkali/transition metal binuclear complexes wherein the macrocycle demonstrated the Janus reactivity with one cavity acting as a porphyrinoid and the other mimicking the crown ether.

Object Details

• Location: Deutsche Nationalbibliothek Frankfurt am Main
• Extent: Online-Ressource
• Language: Englisch

References and Relationships

• Bibliographic citation: Janus Reactivity of Crownphyrinoids: Alkali‐ vs. Transition Metal‐Mediated Transformations of Crown Ether‐Porphyrin Hybrids ; day:23 ; month:10 ; year:2024 ; extent:10 ; Chemistry - a European journal ; (23.10.2024) (gesamt 10)

Contributors, Places and Time

• Creator: Matviyishyn, Maksym ; A. Konieczny, Krzysztof ; Trzaskowski, Bartosz ; Szyszko, Bartosz

Further information

• DOI: 10.1002/chem.202402932
• URN: urn:nbn:de:101:1-2410241425171.620124540288
• Rights: Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
• Last update: 15.08.2025, 7:31 AM CEST