Ligand‐Promoted (Pd)‐Catalyzed α‐Alkylation of Ketones through a Borrowing‐Hydrogen Approach

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Abstract: A new class of palladium complexes bearing bidentate 2‐hydroxypyridine based ligands have been prepared and fully characterized. The applications of these new complexes towards ketone alkylation reactions with alcohols through a metal‐ligand cooperative borrowing‐hydrogen (BH) process were demonstrated.

Location: Deutsche Nationalbibliothek Frankfurt am Main

Extent: Online-Ressource

Language: Englisch

Bibliographic citation: Ligand‐Promoted (Pd)‐Catalyzed α‐Alkylation of Ketones through a Borrowing‐Hydrogen Approach ; volume:12 ; number:1 ; year:2023 ; extent:4
ChemistryOpen ; 12, Heft 1 (2023) (gesamt 4)

Creator: Manojveer, Seetharaman
Garg, Nitish K.
Gul, Zarif
Kanwal, Ayesha
Goriya, Yogesh
Johnson, Magnus T.

DOI: 10.1002/open.202200245

URN: urn:nbn:de:101:1-2023010314073003211731

Rights: Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.

Last update: 15.08.2025, 7:30 AM CEST

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Manojveer, Seetharaman
Garg, Nitish K.
Gul, Zarif
Kanwal, Ayesha
Goriya, Yogesh
Johnson, Magnus T.

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Regioselective α-Alkylation of Ketones via Magnesium Enamides

Iron‐Catalyzed Borrowing Hydrogen C ‐Alkylation of Oxindoles with Alcohols

Site‐Selective Pd‐Catalyzed C(sp 3 )−H Arylation of Heteroaromatic Ketones

Cross‐Coupling of Allenamides and C ‐Based Nucleophiles by Pd‐Catalyzed Allylic Alkylation

Single-Atom Zinc-Catalyzed C/N-Alkylation through Borrowing Hydrogen Processes

The Reetz Alkylation: Direct Geminal Dimethylation of Ketones Using Organotitanium Chemistry

S,O‐Ligand‐Promoted Pd‐Catalyzed C−H Olefination of Anisole Derivatives

Diaminocyclopentadienone Ruthenium Complex Catalyzed Alkylation of Indoles and Ketones with Primary Alcohols

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Iron‐Catalyzed Borrowing Hydrogen C ‐Alkylation of Oxindoles with Alcohols

Site‐Selective Pd‐Catalyzed C(sp 3 )−H Arylation of Heteroaromatic Ketones

Cross‐Coupling of Allenamides and C ‐Based Nucleophiles by Pd‐Catalyzed Allylic Alkylation

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S,O‐Ligand‐Promoted Pd‐Catalyzed C−H Olefination of Anisole Derivatives

Diaminocyclopentadienone Ruthenium Complex Catalyzed Alkylation of Indoles and Ketones with Primary Alcohols

Dynamic Kinetic Resolution Allows Control of Remote Stereochemistry in Asymmetric Hydrogen Borrowing Alkylation

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Ligand‐Promoted (Pd)‐Catalyzed α‐Alkylation of Ketones through a Borrowing‐Hydrogen Approach

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Other Objects (12)

Pd-Catalyzed Allylic Alkylation of Ketones

Functional group tolerant hydrogen borrowing C-alkylation

Regioselective α-Alkylation of Ketones via Magnesium Enamides

Iron‐Catalyzed Borrowing Hydrogen C ‐Alkylation of Oxindoles with Alcohols

Site‐Selective Pd‐Catalyzed C(sp 3 )−H Arylation of Heteroaromatic Ketones

Cross‐Coupling of Allenamides and C ‐Based Nucleophiles by Pd‐Catalyzed Allylic Alkylation

Single-Atom Zinc-Catalyzed C/N-Alkylation through Borrowing Hydrogen Processes

The Reetz Alkylation: Direct Geminal Dimethylation of Ketones Using Organotitanium Chemistry

S,O‐Ligand‐Promoted Pd‐Catalyzed C−H Olefination of Anisole Derivatives

Diaminocyclopentadienone Ruthenium Complex Catalyzed Alkylation of Indoles and Ketones with Primary Alcohols

Dynamic Kinetic Resolution Allows Control of Remote Stereochemistry in Asymmetric Hydrogen Borrowing Alkylation

Dynamic Kinetic Resolution Allows Control of Remote Stereochemistry in Asymmetric Hydrogen Borrowing Alkylation

Pd-Catalyzed Allylic Alkylation of Ketones

Functional group tolerant hydrogen borrowing C-alkylation

Regioselective α-Alkylation of Ketones via Magnesium Enamides

Iron‐Catalyzed Borrowing Hydrogen C ‐Alkylation of Oxindoles with Alcohols

Site‐Selective Pd‐Catalyzed C(sp 3 )−H Arylation of Heteroaromatic Ketones

Cross‐Coupling of Allenamides and C ‐Based Nucleophiles by Pd‐Catalyzed Allylic Alkylation

Single-Atom Zinc-Catalyzed C/N-Alkylation through Borrowing Hydrogen Processes

The Reetz Alkylation: Direct Geminal Dimethylation of Ketones Using Organotitanium Chemistry

S,O‐Ligand‐Promoted Pd‐Catalyzed C−H Olefination of Anisole Derivatives

Diaminocyclopentadienone Ruthenium Complex Catalyzed Alkylation of Indoles and Ketones with Primary Alcohols

Dynamic Kinetic Resolution Allows Control of Remote Stereochemistry in Asymmetric Hydrogen Borrowing Alkylation

Dynamic Kinetic Resolution Allows Control of Remote Stereochemistry in Asymmetric Hydrogen Borrowing Alkylation

Pd-Catalyzed Allylic Alkylation of Ketones

Functional group tolerant hydrogen borrowing C-alkylation

Regioselective α-Alkylation of Ketones via Magnesium Enamides

Iron‐Catalyzed Borrowing Hydrogen C ‐Alkylation of Oxindoles with Alcohols

Site‐Selective Pd‐Catalyzed C(sp 3 )−H Arylation of Heteroaromatic Ketones

Cross‐Coupling of Allenamides and C ‐Based Nucleophiles by Pd‐Catalyzed Allylic Alkylation

Single-Atom Zinc-Catalyzed C/N-Alkylation through Borrowing Hydrogen Processes

The Reetz Alkylation: Direct Geminal Dimethylation of Ketones Using Organotitanium Chemistry

S,O‐Ligand‐Promoted Pd‐Catalyzed C−H Olefination of Anisole Derivatives

Diaminocyclopentadienone Ruthenium Complex Catalyzed Alkylation of Indoles and Ketones with Primary Alcohols

Dynamic Kinetic Resolution Allows Control of Remote Stereochemistry in Asymmetric Hydrogen Borrowing Alkylation

Dynamic Kinetic Resolution Allows Control of Remote Stereochemistry in Asymmetric Hydrogen Borrowing Alkylation

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