Ruthenium Olefin Metathesis Catalysts Bearing a Macrocyclic N‐Heterocyclic Carbene Ligand: Improved Stability and Activity

Abstract: Formation of sterically hindered C−C double bonds via catalytic olefin metathesis is considered a very challenging task for Ru catalysts. This limitation led to the development of specialised catalysts bearing sterically reduced N‐heterocyclic carbene (NHC) ligands that are very active in such transformations, yet significantly less stable as compared to general purpose catalysts. To decrease the small‐size NHC catalysts susceptibility to decomposition, a new NHC ligand was designed, in which two sterically reduced aryl arms were tied together by a C‐8 alkyl chain. The installation of this macrocyclic ligand on the ruthenium centre led to the formation of an olefin metathesis catalyst (trans‐Ru6). Interestingly, this complex undergoes transformation into an isomer bearing two Cl ligands in the cis‐arrangement (cis‐Ru6). These two isomeric complexes exhibit similarly high thermodynamic stability, yet different application profiles in catalysis.

Object Details

• Location: Deutsche Nationalbibliothek Frankfurt am Main
• Extent: Online-Ressource
• Language: Englisch

References and Relationships

• Bibliographic citation: Ruthenium Olefin Metathesis Catalysts Bearing a Macrocyclic N‐Heterocyclic Carbene Ligand: Improved Stability and Activity ; day:13 ; month:04 ; year:2022 ; extent:1 ; Angewandte Chemie / International edition. International edition ; (13.04.2022) (gesamt 1)

Contributors, Places and Time

• Creator: Kośnik, Wioletta ; Lichosyt, Dawid ; Śnieżek, Marcin ; Janaszkiewicz, Angelika ; Woźniak, Krzysztof ; Malińska, Maura ; Trzaskowski, Bartosz ; Kajetanowicz, Anna ; Grela, Karol

Further information

• DOI: 10.1002/anie.202201472
• URN: urn:nbn:de:101:1-2022041415124687572059
• Rights: Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
• Last update: 15.08.2025, 7:35 AM CEST