Mukaiyama-Michael vinylogous additions to nitroalkenes under solvent-free conditions
Abstract: The first Mukaiyama-Michael vinylogous reaction of a dioxinone-derived silyl ether to nitroalkenes is reported. The conjugate addition is performed in absence of any catalyst under solvent-free conditions, proceeding with satisfactory efficiency with variously substituted nitroalkenes. Moreover, the first organocatalyzed Mukaiyama-Michael vinylogous reaction of trimethylsilyloxyfuran to nitroalkenes is described.The reaction is promoted by Brønsted acids under solvent-free conditions, taking place in moderate to good yield with variously substituted nitroalkenes..
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Mukaiyama-Michael vinylogous additions to nitroalkenes under solvent-free conditions ; volume:10 ; number:1 ; year:2012 ; pages:47-53 ; extent:7
Open chemistry ; 10, Heft 1 (2012), 47-53 (gesamt 7)
- Creator
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Scettri, Arrigo
Villano, Rosaria
Manzo, Patrizia
Acocella, Maria
- DOI
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10.2478/s11532-011-0122-7
- URN
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urn:nbn:de:101:1-2410181713424.812435374589
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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15.08.2025, 7:26 AM CEST
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Associated
- Scettri, Arrigo
- Villano, Rosaria
- Manzo, Patrizia
- Acocella, Maria
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