Balancing Attraction and Repulsion: The Influence of London Dispersion in (10) Cycloparaphenylene‐Fullerene Complexes

Abstract: Herein we present a systematic study of the influence of different alkyl chains in malonyl ester fullerene adducts with [10]cycloparaphenylene ([10]CPP]) and a tert‐butyl (tBu) ester‐substituted [10]CPP analogue. The association constants between the nanoring hosts and the fullerene guests were determined by fluorescence quenching experiments. The trends in association were rationalized by an interplay of repulsion arising from an extended volume and London dispersion as an attractive counterpart.

Location
Deutsche Nationalbibliothek Frankfurt am Main
Extent
Online-Ressource
Language
Englisch

Bibliographic citation
Balancing Attraction and Repulsion: The Influence of London Dispersion in (10) Cycloparaphenylene‐Fullerene Complexes ; day:03 ; month:03 ; year:2023 ; extent:7
Chemistry - a European journal ; (03.03.2023) (gesamt 7)

Creator
Volkmann, Jannis
Kohrs, Daniel
Wegner, Hermann A.

DOI
10.1002/chem.202300268
URN
urn:nbn:de:101:1-2023030314404825237996
Rights
Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
Last update
14.08.2025, 11:01 AM CEST

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