Photoinduced Pyridine N‐oxides Catalyzed Carbon Radical Generation from Alkylboronic Acids
Abstract: Herein we report a protocol for the generation of alkyl carbon radicals from alkylboronic acids wherein photoexcited 4‐nitropyridine N‐oxide biradical features a catalyst to promote the nucleo‐homolytic substitution of boronic acids. With a wide range of readily available aliphatic boronic acids, including methyl boronic acid, the developed catalytic system demonstrates broad applicability for alkylation, amination, and cyanation.
- Location
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Deutsche Nationalbibliothek Frankfurt am Main
- Extent
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Online-Ressource
- Language
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Englisch
- Bibliographic citation
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Photoinduced Pyridine N‐oxides Catalyzed Carbon Radical Generation from Alkylboronic Acids ; day:18 ; month:09 ; year:2023 ; extent:7
ChemCatChem ; (18.09.2023) (gesamt 7)
- Creator
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Ascenzi‐Pettenuzzo, Cristina
Nganda, Juliet
Deng, Yongming
- DOI
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10.1002/cctc.202300953
- URN
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urn:nbn:de:101:1-2023091815222414063607
- Rights
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Last update
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14.08.2025, 11:03 AM CEST
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Associated
- Ascenzi‐Pettenuzzo, Cristina
- Nganda, Juliet
- Deng, Yongming
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