Cross‐Regulation of an Artificial Metalloenzyme
Abstract: Cross‐regulation of complex biochemical reaction networks is an essential feature of living systems. In a biomimetic spirit, we report on our efforts to program the temporal activation of an artificial metalloenzyme via cross‐regulation by a natural enzyme. In the presence of urea, urease slowly releases ammonia that reversibly inhibits an artificial transfer hydrogenase. Addition of an acid, which acts as fuel, allows to maintain the system out of equilibrium.
- Standort
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Deutsche Nationalbibliothek Frankfurt am Main
- Umfang
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Online-Ressource
- Sprache
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Englisch
- Erschienen in
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Cross‐Regulation of an Artificial Metalloenzyme ; volume:56 ; number:34 ; year:2017 ; pages:10156-10160 ; extent:5
Angewandte Chemie / International edition. International edition ; 56, Heft 34 (2017), 10156-10160 (gesamt 5)
- Urheber
- DOI
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10.1002/anie.201702181
- URN
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urn:nbn:de:101:1-2022091905565891524912
- Rechteinformation
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Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.
- Letzte Aktualisierung
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15.08.2025, 07:31 MESZ
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Beteiligte
- Okamoto, Yasunori
- Ward, Thomas R.
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