A New Life For Nitrile‐Butadiene Rubber: Co‐Harnessing Metathesis And Condensation For Reincorporation Into Bio‐Based Materials

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Abstract: Efficient plastic recycling processes are crucial for the production of value‐added products or intermediates. Here, we present a multicatalytic route that allows the degradation of nitrile‐butadiene rubber, cross‐metathesis of the formed oligomers, and polymerization of the resulting dicarboxylic acids with bio‐based diols, providing direct access to unsaturated polyesters. This one‐pot approach combines the use of commercially available catalysts that are active and selective under mild conditions to synthesize renewable copolymers without the need to isolate intermediates.

Location: Deutsche Nationalbibliothek Frankfurt am Main

Extent: Online-Ressource

Language: Englisch

Bibliographic citation: A New Life For Nitrile‐Butadiene Rubber: Co‐Harnessing Metathesis And Condensation For Reincorporation Into Bio‐Based Materials ; day:16 ; month:02 ; year:2024 ; extent:7
Angewandte Chemie / International edition. International edition ; (16.02.2024) (gesamt 7)

Creator: Bekmirzaev, Jakhongir
Simon, Malaury
D'Aniello, Sara
Mazzeo, Mina
Cohen‐Janes, Sander J.
Mathers, Robert T.
Gauvin, Régis M.
Thomas, Christophe M.

DOI: 10.1002/anie.202319414

URN: urn:nbn:de:101:1-2024021614332196690546

Rights: Open Access; Der Zugriff auf das Objekt ist unbeschränkt möglich.

Last update: 15.08.2025, 7:21 AM CEST

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Associated

Bekmirzaev, Jakhongir
Simon, Malaury
D'Aniello, Sara
Mazzeo, Mina
Cohen‐Janes, Sander J.
Mathers, Robert T.
Gauvin, Régis M.
Thomas, Christophe M.

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A New Life For Nitrile‐Butadiene Rubber: Co‐Harnessing Metathesis And Condensation For Reincorporation Into Bio‐Based Materials

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One‐step Synthesis of End‐Functionalized Hydrogenated Nitrile‐Butadiene Rubber by Combining the Functional Metathesis with Hydrogenation

Characterization of recycled nitrile butadiene rubber industrial scraps

Characterization of recycled nitrile butadiene rubber industrial scraps

Reuse of Electric Arc Furnace Slag as Filler for Nitrile Butadiene Rubber

Reuse of Electric Arc Furnace Slag as Filler for Nitrile Butadiene Rubber

How the hindered amines affect the microstructure and mechanical properties of nitrile-butadiene rubber composites

How the hindered amines affect the microstructure and mechanical properties of nitrile-butadiene rubber composites

Influence of modified biopolymers on thermal properties and biodegradation processes of carboxylated nitrile-butadiene (XNBR) nanocomposities

Influence of modified biopolymers on thermal properties and biodegradation processes of carboxylated nitrile-butadiene (XNBR) nanocomposities

1,3-Dipoles: Nitrile Imines, Nitrile Oxides and Nitrile Sulfides

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Microstructure–properties relationship in ethylene-propylene diene monomer (EPDM)/nitrile butadiene rubber (NBR)/halloysite nanotubes (HNTs) nanocomposites

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Improved high-temperature damping performance of nitrile-butadiene rubber/phenolic resin composites by introducing different hindered amine molecules

Improved high-temperature damping performance of nitrile-butadiene rubber/phenolic resin composites by introducing different hindered amine molecules

Transport properties of carboxylated nitrile butadiene rubber (XNBR)-nanoclay composites; a promising material for protective gloves in occupational exposures

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Influence of Silica (SiO2) Loading on the Thermal and Swelling Properties of Hydrogenated-Nitrile-Butadiene-Rubber/Silica (HNBR/Silica) Composites

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A New Life For Nitrile‐Butadiene Rubber: Co‐Harnessing Metathesis And Condensation For Reincorporation Into Bio‐Based Materials

A New Life For Nitrile‐Butadiene Rubber: Co‐Harnessing Metathesis And Condensation For Reincorporation Into Bio‐Based Materials

One‐step Synthesis of End‐Functionalized Hydrogenated Nitrile‐Butadiene Rubber by Combining the Functional Metathesis with Hydrogenation

One‐step Synthesis of End‐Functionalized Hydrogenated Nitrile‐Butadiene Rubber by Combining the Functional Metathesis with Hydrogenation

Characterization of recycled nitrile butadiene rubber industrial scraps

Characterization of recycled nitrile butadiene rubber industrial scraps

Reuse of Electric Arc Furnace Slag as Filler for Nitrile Butadiene Rubber

Reuse of Electric Arc Furnace Slag as Filler for Nitrile Butadiene Rubber

How the hindered amines affect the microstructure and mechanical properties of nitrile-butadiene rubber composites

How the hindered amines affect the microstructure and mechanical properties of nitrile-butadiene rubber composites

Influence of modified biopolymers on thermal properties and biodegradation processes of carboxylated nitrile-butadiene (XNBR) nanocomposities

Influence of modified biopolymers on thermal properties and biodegradation processes of carboxylated nitrile-butadiene (XNBR) nanocomposities

1,3-Dipoles: Nitrile Imines, Nitrile Oxides and Nitrile Sulfides

1,3-Dipoles: Nitrile Imines, Nitrile Oxides and Nitrile Sulfides

Microstructure–properties relationship in ethylene-propylene diene monomer (EPDM)/nitrile butadiene rubber (NBR)/halloysite nanotubes (HNTs) nanocomposites

Microstructure–properties relationship in ethylene-propylene diene monomer (EPDM)/nitrile butadiene rubber (NBR)/halloysite nanotubes (HNTs) nanocomposites

A Facile Scalable Strategy for Constructing Novel Robust Self‐Healing Glove Utilizing Nanoreinforced Thermoreversible Carboxylated Nitrile Butadiene Rubber

A Facile Scalable Strategy for Constructing Novel Robust Self‐Healing Glove Utilizing Nanoreinforced Thermoreversible Carboxylated Nitrile Butadiene Rubber

Improved high-temperature damping performance of nitrile-butadiene rubber/phenolic resin composites by introducing different hindered amine molecules

Improved high-temperature damping performance of nitrile-butadiene rubber/phenolic resin composites by introducing different hindered amine molecules

Transport properties of carboxylated nitrile butadiene rubber (XNBR)-nanoclay composites; a promising material for protective gloves in occupational exposures

Transport properties of carboxylated nitrile butadiene rubber (XNBR)-nanoclay composites; a promising material for protective gloves in occupational exposures

Influence of Silica (SiO2) Loading on the Thermal and Swelling Properties of Hydrogenated-Nitrile-Butadiene-Rubber/Silica (HNBR/Silica) Composites

Influence of Silica (SiO2) Loading on the Thermal and Swelling Properties of Hydrogenated-Nitrile-Butadiene-Rubber/Silica (HNBR/Silica) Composites

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